Ocean acidification in the context of Fossil fuel


Ocean acidification in the context of Fossil fuel

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⭐ Core Definition: Ocean acidification

Ocean acidification is the ongoing decrease in the pH of the Earth's ocean. Between 1950 and 2020, the average pH of the ocean surface fell from approximately 8.15 to 8.05. Carbon dioxide emissions from human activities are the primary cause of ocean acidification, with atmospheric carbon dioxide (CO2) levels exceeding 422 ppm (as of 2024). CO2 from the atmosphere is absorbed by the oceans. This chemical reaction produces carbonic acid (H2CO3) which dissociates into a bicarbonate ion (HCO3) and a hydrogen ion (H). The presence of free hydrogen ions (H) lowers the pH of the ocean, increasing acidity (this does not mean that seawater is acidic yet; it is still alkaline, with a pH higher than 8). Marine calcifying organisms, such as mollusks and corals, are especially vulnerable because they rely on calcium carbonate to build shells and skeletons.

A change in pH by 0.1 represents a 26% increase in hydrogen ion concentration in the world's oceans (the pH scale is logarithmic, so a change of one in pH units is equivalent to a tenfold change in hydrogen ion concentration). Sea-surface pH and carbonate saturation states vary depending on ocean depth and location. Colder and higher latitude waters are capable of absorbing more CO2. This can cause acidity to rise, lowering the pH and carbonate saturation levels in these areas. There are several other factors that influence the atmosphere-ocean CO2 exchange, and thus local ocean acidification. These include ocean currents and upwelling zones, proximity to large continental rivers, sea ice coverage, and atmospheric exchange with nitrogen and sulfur from fossil fuel burning and agriculture.

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Ocean acidification in the context of Human impact on the environment

Human impact on the environment (or anthropogenic environmental impact) refers to changes to biophysical environments and to ecosystems, biodiversity, and natural resources caused directly or indirectly by humans. Modifying the environment to fit the needs of society (as in the built environment) is causing severe effects including global warming, environmental degradation (such as ocean acidification), mass extinction and biodiversity loss, ecological crisis, and ecological collapse. Some human activities that cause damage (either directly or indirectly) to the environment on a global scale include population growth, neoliberal economic policies and rapid economic growth, overconsumption, overexploitation, pollution, and deforestation. Some of the problems, including global warming and biodiversity loss, have been proposed as representing catastrophic risks to the survival of the human species.

The term anthropogenic designates an effect or object resulting from human activity. The term was first used in the technical sense by Russian geologist Alexey Pavlov, and it was first used in English by British ecologist Arthur Tansley in reference to human influences on climax plant communities. The atmospheric scientist Paul Crutzen introduced the term "Anthropocene" in the mid-1970s. The term is sometimes used in the context of pollution produced from human activity since the start of the Agricultural Revolution but also applies broadly to all major human impacts on the environment. Many of the actions taken by humans that contribute to a heated environment stem from the burning of fossil fuel from a variety of sources, such as electricity, cars, planes, space heating, manufacturing, or the destruction of forests.

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Ocean acidification in the context of Climate change

Present-day climate change includes both global warming—the ongoing increase in global average temperature—and its wider effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to Earth's climate. The modern-day rise in global temperatures is driven by human activities, especially fossil fuel (coal, oil and natural gas) burning since the Industrial Revolution. Fossil fuel use, deforestation, and some agricultural and industrial practices release greenhouse gases. These gases absorb some of the heat that the Earth radiates after it warms from sunlight, warming the lower atmosphere. Carbon dioxide, the primary gas driving global warming, has increased in concentration by about 50% since the pre-industrial era to levels not seen for millions of years.

Climate change has an increasingly large impact on the environment. Deserts are expanding, while heat waves and wildfires are becoming more common. Amplified warming in the Arctic has contributed to thawing permafrost, retreat of glaciers and sea ice decline. Higher temperatures are also causing more intense storms, droughts, and other weather extremes. Rapid environmental change in mountains, coral reefs, and the Arctic is forcing many species to relocate or become extinct. Even if efforts to minimize future warming are successful, some effects will continue for centuries. These include ocean heating, ocean acidification and sea level rise.

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Ocean acidification in the context of Marine chemistry

Marine chemistry, also known as ocean chemistry or chemical oceanography, is the study of the chemical composition and processes of the world’s oceans, including the interactions between seawater, the atmosphere, the seafloor, and marine organisms. This field encompasses a wide range of topics, such as the cycling of elements like carbon, nitrogen, and phosphorus, the behavior of trace metals, and the study of gases and nutrients in marine environments. Marine chemistry plays a crucial role in understanding global biogeochemical cycles, ocean circulation, and the effects of human activities, such as pollution and climate change, on oceanic systems. It is influenced by plate tectonics and seafloor spreading, turbidity, currents, sediments, pH levels, atmospheric constituents, metamorphic activity, and ecology.

The impact of human activity on the chemistry of the Earth's oceans has increased over time, with pollution from industry and various land-use practices significantly affecting the oceans. Moreover, increasing levels of carbon dioxide in the Earth's atmosphere have led to ocean acidification, which has negative effects on marine ecosystems. The international community has agreed that restoring the chemistry of the oceans is a priority, and efforts toward this goal are tracked as part of Sustainable Development Goal 14.

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Ocean acidification in the context of Planetary integrity

Planetary boundaries are a framework to describe limits to the impacts of human activities on the Earth system. Beyond these limits, the environment may not be able to continue to self-regulate. This would mean the Earth system would leave the period of stability of the Holocene, in which human society developed.

These nine boundaries are climate change, ocean acidification, stratospheric ozone depletion, biogeochemical flows in the nitrogen cycle, excess global freshwater use, land system change, the erosion of biosphere integrity, chemical pollution, and atmospheric aerosol loading.

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Ocean acidification in the context of Effects of climate change

Effects of climate change are well documented and growing for Earth's natural environment and human societies. Changes to the climate system include an overall warming trend, changes to precipitation patterns, and more extreme weather. As the climate changes it impacts the natural environment with effects such as more intense forest fires, thawing permafrost, and desertification. These changes impact ecosystems and societies, and can become irreversible once tipping points are crossed. Climate activists are engaged in a range of activities around the world that seek to ameliorate these issues or prevent them from happening.

The effects of climate change vary in timing and location. Up until now the Arctic has warmed faster than most other regions due to climate change feedbacks. Surface air temperatures over land have also increased at about twice the rate they do over the ocean, causing intense heat waves. These temperatures would stabilize if greenhouse gas emissions were brought under control. Ice sheets and oceans absorb the vast majority of excess heat in the atmosphere, delaying effects there but causing them to accelerate and then continue after surface temperatures stabilize. Sea level rise is a particular long term concern as a result. The effects of ocean warming also include marine heatwaves, ocean stratification, deoxygenation, and changes to ocean currents. The ocean is also acidifying as it absorbs carbon dioxide from the atmosphere.

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Ocean acidification in the context of Human impact on marine life

Human activities affect marine life and marine habitats through overfishing, habitat loss, the introduction of invasive species, ocean pollution, ocean acidification and ocean warming. These impact marine ecosystems and food webs and may result in consequences as yet unrecognised for the biodiversity and continuation of marine life forms.

The ocean can be described as the world's largest ecosystem and it is home for many species of marine life. Different activities carried out and caused by human beings such as global warming, ocean acidification, and pollution affect marine life and its habitats. For the past 50 years, more than 90 percent of global warming resulting from human activity has been absorbed into the ocean. This results in the rise of ocean temperatures and ocean acidification which is harmful to many fish species and causes damage to habitats such as coral. With coral producing materials such as carbonate rock and calcareous sediment, this creates a unique and valuable ecosystem not only providing food/homes for marine creatures but also having many benefits for humans too. Ocean acidification caused by rising levels of carbon dioxide leads to coral bleaching where the rates of calcification is lowered affecting coral growth. Additionally, another issue caused by humans which impacts marine life is marine plastic pollution, which poses a threat to marine life. According to the IPCC (2019), since 1950 "many marine species across various groups have undergone shifts in geographical range and seasonal activities in response to ocean warming, sea ice change and biogeochemical changes, such as oxygen loss, to their habitats."

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Ocean acidification in the context of Jurassic

The Jurassic (/ʊˈræsɪk/ juurr-ASS-ik) is a geologic period and stratigraphic system that spanned from the end of the Triassic Period 201.4 Ma (million years ago) to the beginning of the Cretaceous Period, 143.1 Ma. The Jurassic constitutes the second and middle period of the Mesozoic Era as well as the eighth period of the Phanerozoic Eon and is named after the Jura Mountains, where limestone strata from the period were first identified.

The start of the Jurassic was marked by the major Triassic–Jurassic extinction event, associated with the eruption of the Central Atlantic Magmatic Province (CAMP). The beginning of the Toarcian Age started around 183 Ma and is marked by the Toarcian Oceanic Anoxic Event, a global episode of oceanic anoxia, ocean acidification, and elevated global temperatures associated with extinctions, likely caused by the eruption of the Karoo-Ferrar large igneous provinces. The end of the Jurassic, however, has no clear, definitive boundary with the Cretaceous and is the only boundary between geological periods to remain formally undefined.

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Ocean acidification in the context of Carbon dioxide in the atmosphere of Earth

In the atmosphere of Earth, carbon dioxide is a trace gas that plays an integral part in the greenhouse effect, carbon cycle, photosynthesis, and oceanic carbon cycle. It is one of three main greenhouse gases in the atmosphere of Earth. The concentration of carbon dioxide (CO2) in the atmosphere reached 427 ppm (0.0427%) on a molar basis in 2024, representing 3341 gigatonnes of CO2. This is an increase of 50% since the start of the Industrial Revolution, up from 280 ppm during the 10,000 years prior to the mid-18th century. The increase is due to human activity.

The current increase in CO2 concentrations is primarily driven by the burning of fossil fuels. Other significant human activities that emit CO2 include cement production, deforestation, and biomass burning. The increase in atmospheric concentrations of CO2 and other long-lived greenhouse gases such as methane increase the absorption and emission of infrared radiation by the atmosphere. This has led to a rise in average global temperature and ocean acidification. Another direct effect is the CO2 fertilization effect. The increase in atmospheric concentrations of CO2 causes a range of further effects of climate change on the environment and human living conditions.

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Ocean acidification in the context of Climate change in the Arctic

Due to climate change in the Arctic, this polar region is expected to become "profoundly different" by 2050. The speed of change is "among the highest in the world", with warming occurring at 3-4 times faster than the global average. This warming has already resulted in the profound Arctic sea ice decline, the accelerating melting of the Greenland ice sheet and the thawing of the permafrost landscape. These ongoing transformations are expected to be irreversible for centuries or even millennia.

Natural life in the Arctic is affected greatly. As the tundra warms, its soil becomes more hospitable to earthworms and larger plants, and the boreal forests spread to the north - yet this also makes the landscape more prone to wildfires, which take longer to recover from than in the other regions. Beavers also take advantage of this warming to colonize the Arctic rivers, and their dams contributing to methane emissions due to the increase in stagnant waters. The Arctic Ocean has experienced a large increase in the marine primary production as warmer waters and less shade from sea ice benefit phytoplankton. At the same time, it is already less alkaline than the rest of the global ocean, so ocean acidification caused by the increasing CO2 concentrations is more severe, threatening some forms of zooplankton such as pteropods.

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Ocean acidification in the context of Cretaceous–Paleogene extinction event

The Cretaceous–Paleogene (K–Pg) extinction event, formerly known as the Cretaceous-Tertiary (K–T) extinction event, was a major mass extinction of three-quarters of the plant and animal species on Earth approximately 66 million years ago. The event caused the extinction of all non-avian dinosaurs. Most other tetrapods weighing more than 25 kg (55 lb) also became extinct, with the exception of some ectothermic species such as sea turtles and crocodilians. It marked the end of the Cretaceous period, and with it the Mesozoic era, while heralding the beginning of the current geological era, the Cenozoic Era. In the geologic record, the K–Pg event is marked by a thin layer of sediment called the K–Pg boundary or K–T boundary, which can be found throughout the world in marine and terrestrial rocks. The boundary clay shows unusually high levels of the metal iridium, which is more common in asteroids than in the Earth's crust.

As originally proposed in 1980 by a team of scientists led by Luis Alvarez and his son Walter, it is now generally thought that the K–Pg extinction resulted from the impact of a massive asteroid 10 to 15 km (6 to 9 mi) wide, 66 million years ago, causing the Chicxulub impact crater and devastating the global environment, mainly through a lingering impact winter which halted photosynthesis in plants and plankton. The impact hypothesis, also known as the Alvarez hypothesis, was bolstered by the discovery of the 180 km (112 mi) Chicxulub crater in the Gulf of Mexico's Yucatán Peninsula in the early 1990s. The temporal match between the ejecta layer, and the onset of the extinctions and the agreement of ecological patterns in the fossil record with modeled environmental perturbations (for example, darkness and cooling), lead to the conclusion that the Chicxulub impact triggered the mass extinction. A 2016 drilling project into the Chicxulub peak ring confirmed that the peak ring comprised granite ejected within minutes from deep in the Earth, but contained hardly any gypsum, the usual sulfate-containing sea floor rock in the region: the gypsum would have vaporized and dispersed as an aerosol into the atmosphere, causing longer-term effects on the climate and food chain. In October 2019, researchers proposed the mechanisms of the mass extinction, arguing that the Chicxulub asteroid impact event rapidly acidified the oceans and produced long-lasting effects on the climate.

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Ocean acidification in the context of Permian–Triassic extinction event

The Permian–Triassic extinction event, colloquially known as the Great Dying, was an extinction event that occurred approximately 251.9 million years ago (mya), at the boundary between the Permian and Triassic geologic periods, and with them the Paleozoic and Mesozoic eras. It is Earth's most severe known extinction event, with the extinction of 57% of biological families, 62% of genera, 81% of marine species, and 70% of terrestrial vertebrate species. It is also the greatest known mass extinction of insects. It is the greatest of the "Big Five" mass extinctions of the Phanerozoic. There is evidence for one to three distinct pulses, or phases, of extinction.

The scientific consensus is that the main cause of the extinction was the flood basalt volcanic eruptions that created the Siberian Traps, which released sulfur dioxide and carbon dioxide, resulting in euxinia (oxygen-starved, sulfurous oceans), elevated global temperatures,and acidified oceans.The level of atmospheric carbon dioxide rose from around 400 ppm to 2,500 ppm with approximately 3,900 to 12,000 gigatonnes of carbon being added to the ocean-atmosphere system during this period.

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Ocean acidification in the context of Sustainable Development Goal 14

Sustainable Development Goal 14 (Goal 14 or SDG 14) is about "Life below water" and is one of the 17 Sustainable Development Goals established by the United Nations in 2015. The official wording is to "Conserve and sustainably use the oceans, seas and marine resources for sustainable development". The Goal has ten targets to be achieved by 2030. Progress towards each target is being measured with one indicator each time by time.

The first seven targets are outcome targets: Reduce marine pollution; protect and restore ecosystems; reduce ocean acidification; sustainable fishing; conserve coastal and marine areas; end subsidies contributing to overfishing; increase the economic benefits from sustainable use of marine resources. The last three targets are means of implementation targets: To increase scientific knowledge, research and technology for ocean health; support small scale fishers; implement and enforce international sea law. One indicator (14.1.1b) under Goal 14 specifically relates to reducing impacts from marine plastic pollution.

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Ocean acidification in the context of Effects of climate change on oceans

There are many effects of climate change on oceans. One of the most important is an increase in ocean temperatures. More frequent marine heatwaves are linked to this. The rising temperature contributes to a rise in sea levels due to the expansion of water as it warms and the melting of ice sheets on land. Other effects on oceans include sea ice decline, reducing pH values and oxygen levels, as well as increased ocean stratification. All this can lead to changes of ocean currents, for example a weakening of the Atlantic meridional overturning circulation (AMOC). The main cause of these changes are the emissions of greenhouse gases from human activities, mainly burning of fossil fuels and deforestation. Carbon dioxide and methane are examples of greenhouse gases. The additional greenhouse effect leads to ocean warming because the ocean takes up most of the additional heat in the climate system. The ocean also absorbs some of the extra carbon dioxide that is in the atmosphere. This causes the pH value of the seawater to drop. Scientists estimate that the ocean absorbs about 25% of all human-caused CO2 emissions.

The various layers of the oceans have different temperatures. For example, the water is colder towards the bottom of the ocean. This temperature stratification will increase as the ocean surface warms due to rising air temperatures. Connected to this is a decline in mixing of the ocean layers, so that warm water stabilises near the surface. A reduction of cold, deep water circulation follows. The reduced vertical mixing makes it harder for the ocean to absorb heat. So a larger share of future warming goes into the atmosphere and land. One result is an increase in the amount of energy available for tropical cyclones and other storms. Another result is a decrease in nutrients for fish in the upper ocean layers. These changes also reduce the ocean's capacity to store carbon. At the same time, contrasts in salinity are increasing. Salty areas are becoming saltier and fresher areas less salty.

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Ocean acidification in the context of Carbonic acid

Carbonic acid is a chemical compound with the chemical formula H2CO3. The molecule rapidly converts to water and carbon dioxide in the presence of water. The interconversion of carbon dioxide and carbonic acid is related to the breathing cycle of animals and the acidification of natural waters.

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