Nitroglycerin in the context of "Autoignition temperature"

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⭐ Core Definition: Nitroglycerin

Nitroglycerin (NG) (alternative spelling nitroglycerine), also known as trinitroglycerol (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless or pale yellow, oily, explosive liquid most commonly produced by nitrating glycerol with white fuming nitric acid under conditions appropriate to the formation of the nitric acid ester. Chemically, the substance is a nitrate ester rather than a nitro compound, but the traditional name is retained. Discovered in 1846 by Ascanio Sobrero, nitroglycerin has been used as an active ingredient in the manufacture of explosives, namely dynamite, and as such it is employed in the construction, demolition, and mining industries. It is combined with nitrocellulose to form double-based smokeless powder, used as a propellant in artillery and firearms since the 1880s.

As is the case for many other explosives, nitroglycerin becomes more and more prone to exploding (i.e., spontaneous decomposition) as the temperature is increased. Upon exposure to heat above 218 °C at sea-level atmospheric pressure, nitroglycerin becomes extremely unstable and tends to explode. When placed in vacuum, it has an autoignition temperature of 270 °C instead. With a melting point of 12.8 °C, the chemical is almost always encountered as a thick and viscous fluid, changing to a crystalline solid when frozen. Although the pure compound itself is colorless, in practice the presence of nitric oxide impurities left over during production tends to give it a slight yellowish tint.

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Nitroglycerin in the context of Corn oil

Corn oil (North American) or maize oil (British) is oil extracted from the germ of corn (maize). Its main use is in cooking, where its high smoke point makes refined corn oil a valuable frying oil. It is also a key ingredient in some margarines. Corn oil is generally less expensive than most other types of vegetable oils.

Corn oil is also a feedstock used for biodiesel. Other industrial uses for corn oil include soap, salve, paint, erasers, rustproofing for metal surfaces, inks, textiles, nitroglycerin, and insecticides. It is sometimes used as a carrier for drug molecules in pharmaceutical preparations. Due to its low cost, corn oil is also one of the most popular choices for use in egg addling, an avian population control method in which a bird's egg is coated with oil to prevent the embryo from receiving oxygen.

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Nitroglycerin in the context of Nitration

In organic chemistry, nitration is a general class of chemical processes for the introduction of a nitro group (−NO2) into an organic compound. The term also is applied incorrectly to the different process of forming nitrate esters (−ONO2) between alcohols and nitric acid (as occurs in the synthesis of nitroglycerin). The difference between the resulting molecular structures of nitro compounds and nitrates (NO3) is that the nitrogen atom in nitro compounds is directly bonded to a non-oxygen atom (typically carbon or another nitrogen atom), whereas in nitrate esters (also called organic nitrates), the nitrogen is bonded to an oxygen atom that in turn usually is bonded to a carbon atom (nitrito group).

There are many major industrial applications of nitration in the strict sense; the most important by volume are for the production of nitroaromatic compounds such as nitrobenzene. The technology is long-standing and mature.

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Nitroglycerin in the context of Dynamite

Dynamite is an explosive made of nitroglycerin, sorbents (such as powdered shells or clay), and stabilizers. It was invented by the Swedish chemist and engineer Alfred Nobel in Geesthacht, Northern Germany, and was patented in 1867. It rapidly gained wide-scale use as a more robust alternative to the traditional black powder explosives. It allows the use of nitroglycerine's favorable explosive properties while greatly reducing its risk of accidental detonation.

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Nitroglycerin in the context of Alfred Nobel

Alfred Bernhard Nobel (/nˈbɛl/ noh-BEL; Swedish: [ˈǎlfrɛd nʊˈbɛlː] ; 21 October 1833 – 10 December 1896) was a Swedish chemist, inventor, engineer, and businessman. He is known for inventing dynamite, as well as having bequeathed his fortune to establish the Nobel Prizes. He also made several other important contributions to science, holding 355 patents during his life.

Born into the prominent Nobel family in Stockholm, Nobel displayed an early aptitude for science and learning, particularly in chemistry and languages; he became fluent in six languages and filed his first patent at the age of 24. He embarked on many business ventures with his family, most notably owning the company Bofors—which was an iron and steel producer that he had developed into a major manufacturer of cannons and other armaments. Nobel's most famous invention, dynamite, was an explosive made using nitroglycerin, which was patented in 1867. He further invented gelignite in 1875 and ballistite in 1887.

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Nitroglycerin in the context of Pentaerythritol tetranitrate

Pentaerythritol tetranitrate (PETN), also known as PENT, pentyl, PENTA (ПЕНТА, primarily in Russian), TEN (tetraeritrit nitrate), corpent, or penthrite (or, rarely and primarily in German, as nitropenta), is an explosive material. It is the nitrate ester of pentaerythritol, and is structurally very similar to nitroglycerin. Penta refers to the five carbon atoms of the neopentane skeleton. PETN is a very powerful explosive material with a relative effectiveness factor of 1.66. When mixed with a plasticizer, PETN forms a plastic explosive. Along with RDX it is the main ingredient of Semtex.

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Nitroglycerin in the context of Buccal administration

Buccal administration is a topical route of administration by which drugs held or applied in the buccal (/ˈbʌkəl/) area (in the cheek) diffuse through the oral mucosa (tissues which line the mouth) and enter directly into the bloodstream. Buccal administration may provide better bioavailability of some drugs and a more rapid onset of action compared to oral administration because the medication does not pass through the digestive system and thereby avoids first pass metabolism. Drug forms for buccal administration include tablets and thin films.

As of May 2014, the psychiatric drug asenapine; the opioid drugs buprenorphine, naloxone, and fentanyl; the cardiovascular drug nitroglycerin; the nausea medication prochlorperazine; the hormone replacement therapy testosterone; and nicotine as a smoking cessation aid were commercially available in buccal forms, as was midazolam, an anticonvulsant, used to treat acute epileptic seizures.

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Nitroglycerin in the context of Nitrate ester

In organic chemistry, a nitrate ester is an organic functional group with the formula R−ONO2, where R stands for any organyl group. They are the esters of nitric acid and alcohols. A well-known example is nitroglycerin, which is not a nitro compound, despite its name.

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