Nickel(II) oxide in the context of Nickel(III) oxide

Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slow to react with air under standard conditions because a passivation layer of nickel oxide that prevents further corrosion forms on the surface. Even so, pure native nickel is found in Earth's crust only in tiny amounts, usually in ultramafic rocks, and in the interiors of larger nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere.

Meteoric nickel is found in combination with iron, a reflection of the origin of those elements as major end products of supernova nucleosynthesis. An iron–nickel mixture is thought to compose Earth's outer and inner cores.

Bunsenite is the naturally occurring form of nickel(II) oxide, NiO. It occurs as rare dark green crystal coatings. It crystallizes in the cubic crystal system and occurs as well formed cubic, octahedral and dodecahedral crystals. It is a member of the periclase group.

It was first described in 1868 for a sample from a hydrothermal nickel–uranium vein from Johanngeorgenstadt, Ore Mountains, Saxony, Germany and named for German chemist Robert Bunsen (1811–1899). Other occurrences include west of the Scotia talc mine near Bon Accord, Barberton district, Transvaal, South Africa and from Kambalda south of Kalgoorlie, Western Australia. The South African occurrence has evidence of thermal metamorphism of a nickel-rich meteorite. It occurs associated with native bismuth, annabergite, aerugite, xanthiosite in Germany; and with liebenbergite, trevorite, nickeloan serpentine, nickeloan ludwigite, violarite, millerite, gaspeite, nimite and bonaccordite in the South African occurrence.