Metalorganics in the context of Metalorganic vapour phase epitaxy


Metalorganics in the context of Metalorganic vapour phase epitaxy

⭐ Core Definition: Metalorganics

Metal-organic compounds (jargon: metalorganics, metallo-organics) are a class of chemical compounds that contain metals and organic ligands, but lacking direct metal-carbon bonds. Metal β-diketonates, metal alkoxides, metal dialkylamides, transition metal carboxylate complexes, metal acetylacetonates, and metal phosphine complexes are representative members of this class. Some of metal-organic compounds confer solubility in organic solvents or volatility. Compounds with these properties find applications in materials science for metal organic vapor deposition (MOCVD) or sol-gel processing. Precise definitions of metal-organic compound may vary, however the term may describe:

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Metalorganics in the context of Organometallic chemistry

Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkali, alkaline earth, and transition metals, and sometimes broadened to include metalloids like boron, silicon, and selenium, as well. Aside from bonds to organyl fragments or molecules, bonds to 'inorganic' carbon, like carbon monoxide (metal carbonyls), cyanide, or carbide, are generally considered to be organometallic as well. Some related compounds such as transition metal hydrides and metal phosphine complexes are often included in discussions of organometallic compounds, though strictly speaking, they are not necessarily organometallic. The related but distinct term "metalorganic compound" refers to metal-containing compounds lacking direct metal-carbon bonds but which contain organic ligands. Metal β-diketonates, alkoxides, dialkylamides, and metal phosphine complexes are representative members of this class. The field of organometallic chemistry combines aspects of traditional inorganic and organic chemistry.

Organometallic compounds are widely used both stoichiometrically in research and industrial chemical reactions, as well as in the role of catalysts to increase the rates of such reactions (e.g., as in uses of homogeneous catalysis), where target molecules include polymers, pharmaceuticals, and many other types of practical products.

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