Mesophase in the context of "Phase of matter"

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⭐ Core Definition: Mesophase

In chemistry and chemical physics, a mesophase or mesomorphic phase is a phase of matter intermediate between solid and liquid. Gelatin is a common example of a partially ordered structure in a mesophase. Further, biological structures such as the lipid bilayers of cell membranes are examples of mesophases. Mobile ions in mesophases are either orientationally or rotationally disordered while their centers are located at the ordered sites in the crystal structure. Mesophases with long-range positional order but no orientational order are plastic crystals, whereas those with long-range orientational order but only partial or no positional order are liquid crystals.

Georges Friedel (1922) called attention to the "mesomorphic states of matter" in his scientific assessment of observations of the so-called liquid crystals. Conventionally a crystal is solid, and crystallization converts liquid to solid. The oxymoron of the liquid crystal is resolved through the notion of mesophases. The observations noted an optic axis persisting in materials that had been melted and had begun to flow. The term liquid crystal persists as a colloquialism, but use of the term was criticized in 1993: In The Physics of Liquid Crystals the mesophases are introduced from the beginning:

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Mesophase in the context of List of states of matter

Matter organizes into various phases or states of matter depending on its constituents and external factors like pressure and temperature. Except at extreme temperatures and pressures, atoms form the three classical states of matter: solid, liquid and gas. Complex molecules can also form various mesophases such as liquid crystals, which are intermediate between the liquid and solid phases. At high temperatures or strong electromagnetic fields, atoms become ionized, forming plasma.

At low temperatures, the electrons of solid materials can also organize into various electronic phases of matter, such as the superconducting state, with vanishing resistivity. Magnetic states such as ferromagnetism and antiferromagnetism can also be regarded as phases of matter in which the electronic and nuclear spins organize into different patterns. Such states of matter are studied in condensed matter physics.

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Mesophase in the context of Lyotropic

Lyotropic liquid crystals result when amphiphiles, which are both hydrophobic and hydrophilic, dissolve into a solution that behaves both like a liquid and a solid crystal. This liquid crystalline mesophase includes everyday mixtures like soap and water.

The term lyotropic comes from Ancient Greek λύω (lúō) 'to dissolve' and τροπικός (tropikós) 'change'. Historically, the term was used to describe the common behavior of materials composed of amphiphilic molecules upon the addition of a solvent. Such molecules comprise a hydrophilic (literally 'water-loving') head-group (which may be ionic or non-ionic) attached to a hydrophobic ('water-hating') group.

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