Lithium deuteride in the context of "Nuclear primary"

Lithium (from Ancient Greek: λίθος, líthos, 'stone') is a chemical element; it has symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid element. Like all alkali metals, lithium is highly reactive and flammable, and must be stored in vacuum, inert atmosphere, or inert liquid such as purified kerosene or mineral oil. It exhibits a metallic luster when pure, but quickly corrodes in air to a dull silvery gray, then black tarnish. It does not occur freely in nature, but occurs mainly as pegmatitic minerals, which were once the main source of lithium. Due to its solubility as an ion, it is present in ocean water and is commonly obtained from brines. Lithium metal is isolated electrolytically from a mixture of lithium chloride and potassium chloride.

The nucleus of the lithium atom verges on instability, since the two stable lithium isotopes found in nature have among the lowest binding energies per nucleon of all stable nuclides. Because of its relative nuclear instability, lithium is less common in the Solar System than 25 of the first 32 chemical elements even though its nuclei are very light: it is an exception to the trend that heavier nuclei are less common. For related reasons, lithium has important uses in nuclear physics. The transmutation of lithium atoms to helium in 1932 was the first fully human-made nuclear reaction, and lithium deuteride serves as a fusion fuel in staged thermonuclear weapons.

A thermonuclear weapon, fusion weapon or hydrogen bomb (H-bomb) is a second-generation nuclear weapon, utilizing nuclear fusion. The most destructive weapons ever created, their yields typically exceed first-generation nuclear weapons by twenty times, with far lower mass and volume requirements. Characteristics of fusion reactions can make possible the use of non-fissile depleted uranium as the weapon's main fuel, thus allowing more efficient use of scarce fissile material. Its multi-stage design is distinct from the usage of fusion in simpler boosted fission weapons. The first full-scale thermonuclear test (Ivy Mike) was carried out by the United States in 1952, and the concept has since been employed by at least the five NPT-recognized nuclear-weapon states: the United States, Russia, the United Kingdom, China, and France.

The design of all thermonuclear weapons is believed to be the Teller–Ulam configuration. This relies on radiation implosion, in which X-rays from detonation of the primary stage, a fission bomb, are channelled to compress a separate fusion secondary stage containing thermonuclear fuel, primarily lithium-6 deuteride. During detonation, neutrons convert lithium-6 to helium-4 plus tritium. The heavy isotopes of hydrogen, deuterium and tritium, then undergo a reaction that releases energy and neutrons. For this reason, thermonuclear weapons are often colloquially called hydrogen bombs or H-bombs.

Castle Bravo was the first in a series of high-yield thermonuclear weapon design tests conducted by the United States at Bikini Atoll, Marshall Islands, as part of Operation Castle. Detonated on 1 March 1954, the device remains the most powerful nuclear device ever detonated by the United States and the first lithium deuteride-fueled thermonuclear weapon tested using the Teller–Ulam design. Castle Bravo's yield was 15 megatons of TNT [Mt] (63 PJ), 2.5 times the predicted 6 Mt (25 PJ), due to unforeseen additional reactions involving lithium-7, which led to radioactive contamination in the surrounding area.

Radioactive nuclear fallout, the heaviest of which was in the form of pulverized surface coral from the detonation, fell on residents of Rongelap and Utirik atolls, while the more particulate and gaseous fallout spread around the world. The inhabitants of the islands were evacuated three days later and suffered radiation sickness. Twenty-three crew members of the Japanese fishing vessel Daigo Fukuryū Maru ("Lucky Dragon No. 5") were also contaminated by the heavy fallout, experiencing acute radiation syndrome, including the death six months later of Kuboyama Aikichi, the boat's chief radioman. The blast incited a strong international reaction over atmospheric thermonuclear testing.

A boosted fission weapon usually refers to a type of nuclear bomb that uses a small amount of fusion fuel to increase the rate, and thus yield, of a fission reaction. The fast fusion neutrons released by the fusion reactions add to the fast neutrons released due to fission, allowing for more neutron-induced fission reactions to take place. The rate of fission is thereby greatly increased such that much more of the fissile material undergoes fission before the core explosively disassembles. The fusion process itself adds only a small amount of energy to the process, perhaps 1%. The fuel is commonly a 50-50 deuterium-tritium gas mixture, although lithium-6-deuteride has also been tested.

The alternative meaning is an obsolete type of single-stage nuclear bomb that uses thermonuclear fusion on a large scale to create fast neutrons that can cause fission in depleted uranium, but which is not a two-stage hydrogen bomb. This type of bomb was referred to by Edward Teller as "Alarm Clock", and by Andrei Sakharov as "Sloika" or "Layer Cake" (Teller and Sakharov developed the idea independently, as far as is known).