Lithium in the context of "Nuclide"

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⭐ Core Definition: Lithium

Lithium (from Ancient Greek: λίθος, líthos, 'stone') is a chemical element; it has symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid element. Like all alkali metals, lithium is highly reactive and flammable, and must be stored in vacuum, inert atmosphere, or inert liquid such as purified kerosene or mineral oil. It exhibits a metallic luster when pure, but quickly corrodes in air to a dull silvery gray, then black tarnish. It does not occur freely in nature, but occurs mainly as pegmatitic minerals, which were once the main source of lithium. Due to its solubility as an ion, it is present in ocean water and is commonly obtained from brines. Lithium metal is isolated electrolytically from a mixture of lithium chloride and potassium chloride.

The nucleus of the lithium atom verges on instability, since the two stable lithium isotopes found in nature have among the lowest binding energies per nucleon of all stable nuclides. Because of its relative nuclear instability, lithium is less common in the Solar System than 25 of the first 32 chemical elements even though its nuclei are very light: it is an exception to the trend that heavier nuclei are less common. For related reasons, lithium has important uses in nuclear physics. The transmutation of lithium atoms to helium in 1932 was the first fully human-made nuclear reaction, and lithium deuteride serves as a fusion fuel in staged thermonuclear weapons.

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Lithium in the context of Big Bang

The Big Bang is a physical theory that describes how the universe expanded from an initial state of high density and temperature. Various cosmological models based on the Big Bang concept explain a broad range of phenomena, including the abundance of light elements, the cosmic microwave background (CMB) radiation, and large-scale structure. The uniformity of the universe, known as the horizon and flatness problems, is explained through cosmic inflation: a phase of accelerated expansion during the earliest stages. Detailed measurements of the expansion rate of the universe place the initial singularity at an estimated 13.787±0.02 billion years ago, which is considered the age of the universe. A wide range of empirical evidence strongly favors the Big Bang event, which is now widely accepted.

Extrapolating this cosmic expansion backward in time using the known laws of physics, the models describe an extraordinarily hot and dense primordial universe. Physics lacks a widely accepted theory that can model the earliest conditions of the Big Bang. As the universe expanded, it cooled sufficiently to allow the formation of subatomic particles, and later atoms. These primordial elements—mostly hydrogen, with some helium and lithium—then coalesced under the force of gravity aided by dark matter, forming early stars and galaxies. Measurements of the redshifts of supernovae indicate that the expansion of the universe is accelerating, an observation attributed to a concept called dark energy.

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Lithium in the context of Environmental effects of mining

Environmental impact of mining can occur at local, regional, and global scales through direct and indirect mining practices. Mining can cause erosion, sinkholes, loss of biodiversity, or the contamination of soil, groundwater, and surface water by chemicals emitted from mining processes. These processes also affect the atmosphere through carbon emissions which contributes to climate change.

Some mining methods (lithium mining, phosphate mining, coal mining, mountaintop removal mining, and sand mining) may have such significant environmental and public health effects that mining companies in some countries are required to follow strict environmental and rehabilitation codes to ensure that the mined area returns to its original state. Mining can provide various advantages to societies, yet it can also spark conflicts, particularly regarding land use both above and below the surface.

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Lithium in the context of Ion

An ion (/ˈ.ɒn, -ən/) is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons.

A cation is a positively charged ion with fewer electrons than protons (e.g. K (potassium ion)) while an anion is a negatively charged ion with more electrons than protons (e.g. Cl (chloride ion) and OH (hydroxide ion)). Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed monatomic ions, atomic ions or simple ions, while ions consisting of two or more atoms are termed polyatomic ions or molecular ions.

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Lithium in the context of Alkali metal

The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr). Together with hydrogen they constitute group 1, which lies in the s-block of the periodic table. All alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in them having very similar characteristic properties. Indeed, the alkali metals provide the best example of group trends in properties in the periodic table, with elements exhibiting well-characterised homologous behaviour. This family of elements is also known as the lithium family after its leading element.

The alkali metals are all shiny, soft, highly reactive metals at standard temperature and pressure and readily lose their outermost electron to form cations with charge +1. They can all be cut easily with a knife due to their softness, exposing a shiny surface that tarnishes rapidly in air due to oxidation by atmospheric moisture and oxygen (and in the case of lithium, nitrogen). Because of their high reactivity, they must be stored under oil to prevent reaction with air, and are found naturally only in salts and never as the free elements. Caesium, the fifth alkali metal, is the most reactive of all the metals. All the alkali metals react with water, with the heavier alkali metals reacting more vigorously than the lighter ones.

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Lithium in the context of Stellar nucleosynthesis

In astrophysics, stellar nucleosynthesis is the creation of chemical elements by nuclear fusion reactions within stars. Stellar nucleosynthesis has occurred since the original creation of hydrogen, helium and lithium during the Big Bang. As a predictive theory, it yields accurate estimates of the observed abundances of the elements. It explains why the observed abundances of elements change over time and why some elements and their isotopes are much more abundant than others. The theory was initially proposed by Fred Hoyle in 1946, who later refined it in 1954. Further advances were made, especially to nucleosynthesis by neutron capture of the elements heavier than iron, by Margaret and Geoffrey Burbidge, William Alfred Fowler and Fred Hoyle in their famous 1957 BFH paper, which became one of the most heavily cited papers in astrophysics history.

Stars evolve because of changes in their composition (the abundance of their constituent elements) over their lifespans, first by burning hydrogen (main sequence star), then helium (horizontal branch star), and progressively burning higher elements. However, this does not by itself significantly alter the abundances of elements in the universe as the elements are contained within the star. Later in its life, a low-mass star will slowly eject its atmosphere via stellar wind, forming a planetary nebula, while a higher–mass star will eject mass via a sudden catastrophic event called a supernova. The term supernova nucleosynthesis is used to describe the creation of elements during the explosion of a massive star or white dwarf.

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