Lead–lead dating in the context of Uranium–lead dating

A calcium–aluminium-rich inclusion or Ca–Al-rich inclusion (CAI) is a submillimeter- to centimeter-sized light-colored calcium- and aluminium-rich inclusion found in carbonaceous chondrite meteorites. The first high-precision radiometric datings of CAIs involved four samples examined through the Pb–Pb chronometer, yielding a weighted mean age of 4567.30 ± 0.16 Ma. Subsequent studies including additional samples suggest a slightly older age of 4568.3 ± 0.7 Ma to rectify inconsistencies regarding Hf–W and Al–Mg chronometry methods. As CAIs are the oldest dated solids, this age is commonly used to define the age of the Solar System.

Lead (₈₂Pb) has four observationally stable isotopes: Pb, Pb, Pb, Pb. Lead-204 is entirely a primordial nuclide and is not a radiogenic nuclide. The three isotopes lead-206, lead-207, and lead-208 represent the ends of three decay chains: the uranium series (or radium series), the actinium series, and the thorium series, respectively; a fourth decay chain, the neptunium series, terminates with the thallium isotope Tl. The three series terminating in lead represent the decay chain products of long-lived primordial U, U, and Th. Each isotope also occurs, to some extent, as primordial isotopes that were made in supernovae, rather than radiogenically as daughter products. The fixed ratio of lead-204 to the primordial amounts of the other lead isotopes may be used as the baseline to estimate the extra amounts of radiogenic lead present in rocks as a result of decay from uranium and thorium. This is the basis for lead–lead dating and uranium–lead dating.

The longest-lived radioisotopes, both decaying by electron capture, are Pb with a half-life of 17.0 million years and Pb with a half-life of 52,500 years. A shorter-lived naturally occurring radioisotope, Pb with a half-life of 22.2 years, is useful for studying the sedimentation chronology of environmental samples on time scales shorter than 100 years.