Laws of thermodynamics in the context of "Physical law"

Waste heat is heat that is produced by a machine, or other process that uses energy, as a byproduct of doing work. All such processes give off some waste heat as a fundamental result of the laws of thermodynamics. Waste heat has lower utility (or in thermodynamics lexicon a lower exergy or higher entropy) than the original energy source. Sources of waste heat include all manner of human activities, natural systems, and all organisms, for example, incandescent light bulbs get hot, a refrigerator warms the room air, a building gets hot during peak hours, an internal combustion engine generates high-temperature exhaust gases, and electronic components get warm when in operation.

Instead of being "wasted" by release into the ambient environment, sometimes waste heat (or cold) can be used by another process (such as using hot engine coolant to heat a vehicle), or a portion of heat that would otherwise be wasted can be reused in the same process if make-up heat is added to the system (as with heat recovery ventilation in a building).

Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantities but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to various topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering, and mechanical engineering, as well as other complex fields such as meteorology.

Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the first to formulate a concise definition of thermodynamics in 1854 which stated, "Thermo-dynamics is the subject of the relation of heat to forces acting between contiguous parts of bodies, and the relation of heat to electrical agency." German physicist and mathematician Rudolf Clausius restated Carnot's principle known as the Carnot cycle and gave the theory of heat a truer and sounder basis. His most important paper, "On the Moving Force of Heat", published in 1850, first stated the second law of thermodynamics. In 1865 he introduced the concept of entropy. In 1870 he introduced the virial theorem, which applied to heat.

William Thomson, 1st Baron Kelvin (26 June 1824 – 17 December 1907), was a British mathematician, mathematical physicist and engineer. Born in Belfast, he was for 53 years the professor of Natural Philosophy at the University of Glasgow, where he undertook significant research on the mathematical analysis of electricity, was instrumental in the formulation of the first and second laws of thermodynamics, and contributed significantly to unifying physics, which was then in its infancy of development as an emerging academic discipline. He received the Royal Society's Copley Medal in 1883 and served as its president from 1890 to 1895. In 1892 he became the first scientist to be elevated to the House of Lords.

Absolute temperatures are stated in units of kelvin in Lord Kelvin's honour. While the existence of a coldest possible temperature, absolute zero, was known before his work, Kelvin determined its correct value as approximately −273.15 degrees Celsius or −459.67 degrees Fahrenheit. The Joule–Thomson effect is also named in his honour.

Perpetual motion is the motion of bodies that continues forever in an unperturbed system. A perpetual motion machine is a hypothetical machine that can do work indefinitely without an external energy source. This kind of machine is impossible, since its existence would violate the first and/or second laws of thermodynamics. These laws of thermodynamics apply regardless of the size of the system. Thus, machines that extract energy from finite sources cannot operate indefinitely because they are driven by the energy stored in the source, which will eventually be exhausted. A common example is devices powered by ocean currents, whose energy is ultimately derived from the Sun, which itself will eventually burn out.

In 2016, new states of matter, time crystals, were discovered in which, on a microscopic scale, the component atoms are in continual repetitive motion, thus satisfying the literal definition of "perpetual motion". However, these do not constitute perpetual motion machines in the traditional sense, or violate thermodynamic laws, because they are in their quantum ground state, so no energy can be extracted from them; they exhibit motion without energy.

Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the study of chemical questions and the spontaneity of processes.

The structure of chemical thermodynamics is based on the first two laws of thermodynamics. Starting from the first and second laws of thermodynamics, four equations called the "fundamental equations of Gibbs" can be derived. From these four, a multitude of equations, relating the thermodynamic properties of the thermodynamic system can be derived using relatively simple mathematics. This outlines the mathematical framework of chemical thermodynamics.

Karl Ludwig von Bertalanffy (19 September 1901 – 12 June 1972) was an Austrian biologist known as one of the founders of general systems theory (GST). This is an interdisciplinary practice that describes systems with interacting components, applicable to biology, cybernetics and other fields. Bertalanffy proposed that the classical laws of thermodynamics might be applied to closed systems, but not necessarily to "open systems" such as living things. His mathematical model of an organism's growth over time, published in 1934, is still in use today.

Bertalanffy grew up in Austria and subsequently worked in Vienna, London, Canada, and the United States.