Intramolecular force in the context of Intermolecular bond


Intramolecular force in the context of Intermolecular bond

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⭐ Core Definition: Intramolecular force

An intramolecular force (from Latin intra- 'within') is any force that binds together the atoms making up a molecule. Intramolecular forces are stronger than the intermolecular forces that govern the interactions between molecules.

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Intramolecular force in the context of Intermolecular force

An intermolecular force (IMF; also secondary force) is the force that mediates interaction between molecules, including the electromagnetic forces of attractionor repulsion which act between atoms and other types of neighbouring particles (e.g. atoms or ions). Intermolecular forces are weak relative to intramolecular forces – the forces which hold a molecule together. For example, the covalent bond, involving sharing electron pairs between atoms, is much stronger than the forces present between neighboring molecules. Both sets of forces are essential parts of force fields frequently used in molecular mechanics.

The first reference to the nature of microscopic forces is found in Alexis Clairaut's work Théorie de la figure de la Terre, published in Paris in 1743. Other scientists who have contributed to the investigation of microscopic forces include: Laplace, Gauss, Maxwell, Boltzmann and Pauling.

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