In chemistry, the mole fraction or molar fraction, also called mole proportion or molar proportion, is a quantity defined as the ratio between the amount of a constituent substance, ni (expressed in unit of moles, symbol mol), and the total amount of all constituents in a mixture, ntot (also expressed in moles):
It is denoted xi (lowercase Roman letter x), sometimes χi (lowercase Greek letter chi). (For mixtures of gases, the letter y is recommended.)
The atmosphere of Earth consists of a layer of mixed gas (commonly referred to as air) that is retained by gravity, surrounding the Earth's surface. It contains variable quantities of suspended aerosols and particulates that create weather features such as clouds and hazes. The atmosphere serves as a protective buffer between the Earth's surface and outer space. It shields the surface from most meteoroids and ultraviolet solar radiation, reduces diurnal temperature variation – the temperature extremes between day and night, and keeps it warm through heat retention via the greenhouse effect. The atmosphere redistributes heat and moisture among different regions via air currents, and provides the chemical and climate conditions that allow life to exist and evolve on Earth.
By mole fraction (i.e., by quantity of molecules), dry air contains 78.08% nitrogen, 20.95% oxygen, 0.93% argon, 0.04% carbon dioxide, and small amounts of other trace gases (see Composition below for more detail). Air also contains a variable amount of water vapor, on average around 1% at sea level, and 0.4% over the entire atmosphere.
Greenhouse gases (GHGs) are the gases in an atmosphere that trap heat, raising the surface temperature of astronomical bodies such as Earth. Unlike other gases, greenhouse gases absorb the radiations that a planet emits, resulting in the greenhouse effect. The Earth is warmed by sunlight, causing its surface to radiate heat, which is then mostly absorbed by greenhouse gases. Without greenhouse gases in the atmosphere, the average temperature of Earth's surface would be about −18 °C (0 °F), rather than the present average of 15 °C (59 °F). Human-induced warming has been increasing at a rate that is unprecedented in the instrumental record, reaching 0.27 [0.2–0.4] °C per decade over 2015–2024. This high rate of warming is caused by a combination of greenhouse gas emissions being at an all-time high of 53.6±5.2 Gt CO2e yr−1 over the last decade (2014–2023), as well as reductions in the strength of aerosol cooling.
The five most abundant greenhouse gases in Earth's atmosphere, listed in decreasing order of average global mole fraction, are: water vapor, carbon dioxide, methane, nitrous oxide, ozone. Other greenhouse gases of concern include chlorofluorocarbons (CFCs and HCFCs), hydrofluorocarbons (HFCs), perfluorocarbons, SF
6, and NF
3. Water vapor causes about half of the greenhouse effect, acting in response to other gases as a climate change feedback.
In the atmosphere of Earth, carbon dioxide is a trace gas that plays an integral part in the greenhouse effect, carbon cycle, photosynthesis, and oceanic carbon cycle. It is one of three main greenhouse gases in the atmosphere of Earth. The concentration of carbon dioxide (CO2) in the atmosphere reached 427 ppm (0.0427%) on a molar basis in 2024, representing 3341 gigatonnes of CO2. This is an increase of 50% since the start of the Industrial Revolution, up from 280 ppm during the 10,000 years prior to the mid-18th century. The increase is due to human activity.
The current increase in CO2 concentrations is primarily driven by the burning of fossil fuels. Other significant human activities that emit CO2 include cement production, deforestation, and biomass burning. The increase in atmospheric concentrations of CO2 and other long-lived greenhouse gases such as methane increase the absorption and emission of infrared radiation by the atmosphere. This has led to a rise in average global temperature and ocean acidification. Another direct effect is the CO2 fertilization effect. The increase in atmospheric concentrations of CO2 causes a range of further effects of climate change on the environment and human living conditions.
In science and engineering, the parts-per notation is a set of pseudo-units to describe the small values of miscellaneous dimensionless quantities, e.g. mole fraction or mass fraction.
Since these fractions are quantity-per-quantity measures, they are pure numbers with no associated units of measurement. Commonly used are
The abundance of the chemical elements is a measure of the occurrences of the chemical elements relative to all other elements in a given environment. Abundance is measured in one of three ways: by mass fraction (in commercial contexts often called weight fraction), by mole fraction (fraction of atoms by numerical count, or sometimes fraction of molecules in gases), or by volume fraction. Volume fraction is a common abundance measure in mixed gases such as planetary atmospheres, and is similar in value to molecular mole fraction for gas mixtures at relatively low densities and pressures, and ideal gas mixtures. Most abundance values in this article are given as mass fractions.
The abundance of chemical elements in the universe is dominated by the large amounts of hydrogen and helium which were produced during Big Bang nucleosynthesis. Remaining elements, making up only about 2% of the universe, were largely produced by supernova nucleosynthesis. Elements with even atomic numbers are generally more common than their neighbors in the periodic table, due to their favorable energetics of formation, described by the Oddo–Harkins rule.