Hydronium in the context of Chemical durability


Hydronium in the context of Chemical durability

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⭐ Core Definition: Hydronium

In chemistry, hydronium (hydroxonium in traditional British English) is the cation [H3O], also written as H3O, the type of oxonium ion produced by protonation of water. It is often viewed as the positive ion present when an Arrhenius acid is dissolved in water, as Arrhenius acid molecules in solution give up a proton (a positive hydrogen ion, H) to the surrounding water molecules (H2O). In fact, acids must be surrounded by more than a single water molecule in order to ionize, yielding aqueous H and conjugate base.

Three main structures for the aqueous proton have garnered experimental support:

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Hydronium in the context of Corrosion-resistant

Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.

In the most common use of the word, this means electrochemical oxidation of a metal reacting with an oxidant such as oxygen (O2, gaseous or dissolved), or H3O ions (H, hydrated protons) present in aqueous solution. Rusting, the formation of red-orange iron oxides, is perhaps the most familiar example of electrochemical corrosion. This type of corrosion typically produces oxides or salts of the original metal and results in a distinctive coloration. Corrosion can also occur in materials other than metals, such as ceramics or polymers, although, in this context, the term degradation is more common. Corrosion degrades the useful properties of materials and structures including mechanical strength, appearance, and permeability to liquids and gases. Corrosive is distinguished from caustic: the former implies mechanical degradation, the latter chemical.

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Hydronium in the context of PH

In chemistry, pH (/pˈh/ or /pˈ/; pee-HAYCH or pee-AYCH) is a logarithmic scale used to specify the acidity or basicity of aqueous solutions. Acidic solutions (solutions with higher concentrations of hydrogen (H) cations) are measured to have lower pH values than basic or alkaline solutions. While the origin of the symbol 'pH' can be traced back to its original inventor, and the 'H' refers clearly to hydrogen, the exact original meaning of the letter 'p' in pH is still disputed; it has since acquired a more general technical meaning that is used in numerous other contexts.

The pH scale is logarithmic and inversely indicates the activity of hydrogen cations in the solution

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Hydronium in the context of Acidic soil

Soil pH is a measure of the acidity or basicity (alkalinity) of a soil. Soil pH is a key characteristic that can be used to make informative analysis both qualitative and quantitatively regarding soil characteristics. pH is defined as the negative logarithm (base 10) of the activity of hydronium ions (H
or, more precisely, H
3
O
aq
) in a solution. In soils, it is measured in a slurry of soil mixed with water (or a salt solution, such as 0.01 M CaCl
2
), and normally falls between 3 and 10, with 7 being neutral. Acid soils have a pH below 7 and alkaline soils have a pH above 7. Ultra-acidic soils (pH < 3.5) and very strongly alkaline soils (pH > 9) are rare.

Soil pH is considered a master variable in soils as it affects many chemical processes. It specifically affects plant nutrient availability by controlling the chemical forms of the different nutrients and influencing the chemical reactions they undergo. The optimum pH range for most plants is between 5.5 and 7.5; however, many plants have adapted to thrive at pH values outside this range.

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Hydronium in the context of Self-ionization of water

The self-ionization of water (also autoionization of water, autoprotolysis of water, autodissociation of water, or simply dissociation of water) is an ionization reaction in pure water or in an aqueous solution, in which a water molecule, H2O, deprotonates (loses the nucleus of one of its hydrogen atoms) to become a hydroxide ion, OH. The hydrogen nucleus, H, immediately protonates another water molecule to form a hydronium cation, H3O. It is an example of autoprotolysis, and exemplifies the amphoteric nature of water.

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Hydronium in the context of Deprotonation

Deprotonation (or dehydronation) is the removal (transfer) of a proton (or hydron, or hydrogen cation), (H) from a Brønsted–Lowry acid in an acid–base reaction. The species formed is the conjugate base of that acid. The complementary process, when a proton is added (transferred) to a Brønsted–Lowry base, is protonation (or hydronation). The species formed is the conjugate acid of that base.

A species that can either accept or donate a proton is referred to as amphiprotic. An example is the H2O (water) molecule, which can gain a proton to form the hydronium ion, H3O, or lose a proton, leaving the hydroxide ion, OH.

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Hydronium in the context of PH indicator

A pH indicator is a halochromic chemical compound added in small amounts to a solution so the pH (acidity or basicity) of the solution can be determined visually or spectroscopically by changes in absorption and/or emission properties. Hence, a pH indicator is a chemical detector for hydronium ions (H3O) or hydrogen ions (H) in the Arrhenius model.

Normally, the indicator causes the color of the solution to change depending on the pH. Indicators can also show change in other physical properties; for example, olfactory indicators show change in their odor. The pH value of a neutral solution is 7.0 at 25 °C (standard laboratory conditions). Solutions with a pH value below 7.0 are considered acidic and solutions with pH value above 7.0 are basic. Since most naturally occurring organic compounds are weak electrolytes, such as carboxylic acids and amines, pH indicators find many applications in biology and analytical chemistry. Moreover, pH indicators form one of the three main types of indicator compounds used in chemical analysis. For the quantitative analysis of metal cations, the use of complexometric indicators is preferred, whereas the third compound class, the redox indicators, are used in redox titrations (titrations involving one or more redox reactions as the basis of chemical analysis).

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Hydronium in the context of Oxonium ion

In chemistry, an oxonium ion is any cation containing an oxygen atom that has three bonds and 1+ formal charge. The simplest oxonium ion is the hydronium ion (H3O).

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