Hydrogen gas in the context of "Combustible"

An airship, dirigible balloon or dirigible is a type of aerostat (lighter-than-air) aircraft that can navigate through the air flying under its own power. Aerostats use buoyancy from a lifting gas that is less dense than the surrounding air to achieve the lift needed to stay airborne.

In early dirigibles, the lifting gas used was hydrogen, due to its high lifting capacity and ready availability, but the inherent flammability led to several fatal accidents that rendered hydrogen airships obsolete. The alternative lifting gas, helium, is not flammable, but is rare and relatively expensive. Significant amounts were first discovered in the United States and for a while helium was only available for airship usage in North America. Most airships built since the 1960s have used helium, though some have used hot air.

Catalytic reforming is a chemical process used to convert naphthas from crude oil into liquid products called reformates, which are premium "blending stocks" for high-octane gasoline. The process converts low-octane linear hydrocarbons (paraffins) into branched alkanes (isoparaffins) and cyclic naphthenes, which are then partially dehydrogenated to produce high-octane aromatic hydrocarbons. The dehydrogenation also produces significant amounts of byproduct hydrogen gas, which is fed into other refinery processes such as hydrocracking and hydrodesulfurization. A side reaction is hydrogenolysis, which produces light hydrocarbons of lower value, such as methane, ethane, propane and butanes.

In addition to a gasoline blending stock, reformate is the main source of aromatic bulk chemicals such as benzene, toluene, xylene and ethylbenzene, which have diverse uses, most importantly as raw materials for conversion into plastics. However, the benzene content of reformate makes it carcinogenic, which has led to governmental regulations effectively requiring further processing to reduce its benzene content.

Hydrogen safety covers the safe production, handling and use of hydrogen, particularly hydrogen gas fuel and liquid hydrogen. Hydrogen possesses the NFPA 704's highest rating of four on the flammability scale because it is flammable when mixed even in small amounts with ordinary air. Ignition can occur at a volumetric ratio of hydrogen to air as low as 4% due to the oxygen in the air and the simplicity and chemical properties of the reaction. However, hydrogen has no rating for innate hazard for reactivity or toxicity. The storage and use of hydrogen poses unique challenges due to its ease of leaking as a gaseous fuel, low-energy ignition, wide range of combustible fuel-air mixtures, buoyancy, and its ability to embrittle metals that must be accounted for to ensure safe operation.

Liquid hydrogen poses additional challenges due to its increased density and the extremely low temperatures needed to keep it in liquid form. Moreover, its demand and use in industry—as rocket fuel, alternative energy storage source, coolant for electric generators in power stations, a feedstock in industrial and chemical processes including production of ammonia and methanol, etc.—has continued to increase, which has led to the increased importance of considerations of safety protocols in producing, storing, transferring, and using hydrogen.