High-level waste (HLW) is a type of nuclear waste created by the irradiation of nuclear fuel in a reactor. Irradiation causes a build-up of fission products and transuranic elements (generated by capture of neutrons) in the fuel. Fission products typically have a much shorter half-life than uranium, which means the irradiated fuel is more radioactive and thus hotter than fresh fuel – high-level waste has heat output of >2 kW/m. At the same time, the fissile material (usually uranium-235) is used up, so that the fuel is no longer able to sustain the operation of the reactor and must be recycled or disposed of as waste.
High-level waste includes spent nuclear fuel itself as well as the byproducts of nuclear reprocessing, which results in liquid raffinates and other waste streams. Liquid wastes are not suitable for disposal, so these are vitrified to convert them into a solid, glass form which is suitable for disposal.