Halide in the context of "Titanium tetrachloride"

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⭐ Core Definition: Halide

In chemistry, a halide (rarely halogenide) is a binary chemical compound, of which one part is a halogen atom and the other part is an element or radical that is less electronegative (or more electropositive) than the halogen, to make a fluoride, chloride, bromide, iodide, astatide, or theoretically tennesside compound. The alkali metals combine directly with halogens under appropriate conditions forming halides of the general formula, MX (X = F, Cl, Br or I). Many salts are halides; the hal- syllable in halide and halite reflects this correlation.

A halide ion is a halogen atom bearing a negative charge. The common halide anions are fluoride (F), chloride (Cl), bromide (Br), and iodide (I). Such ions are present in many ionic halide salts. Halide minerals contain halides. All these halide anions are colorless. Halides also form covalent bonds, examples being colorless TiF4, colorless TiCl4, orange TiBr4, and brown TiI4. The heavier members TiCl4, TiBr4, TiI4 can be distilled readily because they are molecular. The outlier is TiF4, m.p. 284 °C, because it has a polymeric structure. Fluorides often differ from the heavier halides.

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Halide in the context of Halophile

A halophile (from the Greek word for 'salt-loving') is an extremophile that thrives in high salt concentrations. In chemical terms, halophile refers to a Lewis acidic species that has some ability to extract halides from other chemical species.

While most halophiles are classified into the domain Archaea, there are also bacterial halophiles and some eukaryotic species, such as the alga Dunaliella salina and fungus Wallemia ichthyophaga. Some well-known species give off a red color from carotenoid compounds, notably bacteriorhodopsin.

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Halide in the context of Flame color

A flame test is a relatively quick test for the presence of some elements in a sample. The technique is archaic and of questionable reliability, but once was a component of qualitative inorganic analysis. The phenomenon is related to pyrotechnics and atomic emission spectroscopy. The color of the flames is understood through the principles of atomic electron transition and photoemission, where varying elements require distinct energy levels (photons) for electron transitions.

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Halide in the context of Gas-discharge lamp

Gas-discharge lamps are a family of artificial light sources that generate light by sending an electric discharge through an ionized gas, a plasma.

Typically, such lamps use anoble gas (argon, neon, krypton, and xenon) or a mixture of these gases. Some include additional substances, such as mercury, sodium, and metal halides, which are vaporized during start-up to become part of the gas mixture.

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Halide in the context of Halide mineral

Halide minerals are those minerals with a dominant halide anion (F, Cl, Br and I). Complex halide minerals may also have polyatomic anions.

Examples include the following:

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Halide in the context of Halogenated

In chemistry, halogenation is a chemical reaction which introduces one or more halogens into a chemical compound. Halide-containing compounds are pervasive, making this type of transformation important, e.g. in the production of polymers, drugs. This kind of conversion is in fact so common that a comprehensive overview is challenging. This article mainly deals with halogenation using elemental halogens (F2, Cl2, Br2, I2). Halides are also commonly introduced using halide salts and hydrogen halide acids. Many specialized reagents exist for introducing halogens into diverse substrates, e.g. thionyl chloride.

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Halide in the context of Nucleophilic aromatic substitution

A nucleophilic aromatic substitution (SNAr) is a substitution reaction in organic chemistry in which the nucleophile displaces a good leaving group, such as a halide, on an aromatic ring. Aromatic rings are usually nucleophilic, but some aromatic compounds do undergo nucleophilic substitution. Just as normally nucleophilic alkenes can be made to undergo conjugate substitution if they carry electron-withdrawing substituents, so normally nucleophilic aromatic rings also become electrophilic if they have the right substituents.

This reaction differs from a common SN2 reaction, because it happens at a trigonal carbon atom (sp hybridization). The mechanism of SN2 reaction does not occur due to steric hindrance of the benzene ring. In order to attack the C atom, the nucleophile must approach in line with the C-LG (leaving group) bond from the back, where the benzene ring lies. It follows the general rule for which SN2 reactions occur only at a tetrahedral carbon atom.

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Halide in the context of Halorhodopsin


Halorhodopsin is a seven-transmembrane retinylidene protein from microbial rhodopsin family. It is a chloride-specific light-activated ion pump found in archaea known as halobacteria. It is activated by green light wavelengths of approximately 578 nm. Halorhodopsin also shares sequence similarity to channelrhodopsin, a light-gated ion channel.

Halorhodopsin contains the essential light-isomerizable vitamin A derivative all-trans-retinal. Due to the dedication towards discovering the structure and function of this moleculc, halorhodopsin is one of the few membrane proteins whose crystal structure is known. Halorhodopsin uses the energy of green/yellow light to move chloride ions into the cell, overcoming the membrane potential. Beside chlorides it transports other halides and nitrates into the cell. Potassium chloride uptake by cells helps to maintain osmotic balance during cell growth. By performing the same task, light-driven anion pumps can considerably reduce the use of metabolic energy. Halorhodopsin has been the subject of much study and its structure is accurately known. Its properties are similar to those of bacteriorhodopsin, and these two light-driven ion pumps transport cations and anions in opposite directions.

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