Iron(II) sulfate or ferrous sulfate (British English: sulphate instead of sulfate) denotes a range of salts with the formula FeSO4·xH2O. These compounds exist most commonly as the heptahydrate (x = 7), but several values for x are known. The hydrated form is used medically to treat or prevent iron deficiency, and also for industrial applications. Known since ancient times as copperas and as green vitriol (vitriol is an archaic name for hydrated sulfate minerals), the blue-green heptahydrate (hydrate with 7 molecules of water) is the most common form of this material. All the iron(II) sulfates dissolve in water to give the same aquo complex [Fe(H2O)6], which has octahedral molecular geometry and is paramagnetic. The name copperas dates from times when the copper(II) sulfate was known as blue copperas, and perhaps in analogy, iron(II) and zinc sulfate were known respectively as green and white copperas.
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Ferrous sulfate in the context of Lime (material)
Lime is an inorganic material composed primarily of calcium oxides and hydroxides. It is also the name for calcium oxide which is used as an industrial mineral and is made by heating calcium carbonate in a kiln. Calcium oxide can occur as a product of coal-seam fires and in altered limestone xenoliths in volcanic ejecta. The International Mineralogical Association recognizes lime as a mineral with the chemical formula of CaO. The word lime originates with its earliest use as building mortar and has the sense of sticking or adhering.
These materials are still used in large quantities in the manufacture of steel and as building and engineering materials (including limestone products, cement, concrete, and mortar), as chemical feedstocks, for sugar refining, and other uses. Lime industries and the use of many of the resulting products date from prehistoric times in both the Old World and the New World. Lime is used extensively for wastewater treatment with ferrous sulfate.
Ferrous sulfate in the context of Natural dye
Natural dyes are dyes or colorants derived from plants, invertebrates, or minerals. The majority of natural dyes are vegetable dyes from plant sources—roots, berries, bark, leaves, and wood—and other biological sources such as fungi.
Archaeologists have found evidence of textile dyeing dating back to the Neolithic period. In China, dyeing with plants, barks and insects has been traced back more than 5,000 years. The essential process of dyeing changed little over time. Typically, the dye material is put in a pot of water and heated to extract the dye compounds into solution with the water. Then the textiles to be dyed are added to the pot, and held at heat until the desired color is achieved. Textile fibre may be dyed before spinning or weaving ("dyed in the wool"), after spinning ("yarn-dyed") or after weaving ("piece-dyed"). Many natural dyes require the use of substances called mordants to bind the dye to the textile fibres. Mordants (from Latin mordere 'to bite') are metal salts that can form a stable molecular coordination complex with both natural dyes and natural fibres. Historically, the most common mordants were alum (potassium aluminum sulfate—a metal salt of aluminum) and iron (ferrous sulfate). Many other metal salt mordants were also used, but are seldom used now due to modern research evidence of their extreme toxicity either to human health, ecological health, or both. These include salts of metals such as chrome, copper, tin, lead, and others. In addition, a number of non-metal salt substances can be used to assist with the molecular bonding of natural dyes to natural fibres—either on their own, or in combination with metal salt mordants—including tannin from oak galls and a range of other plants/plant parts, "pseudo-tannins", such as plant-derived oxalic acid, and ammonia from stale urine. Plants that bio-accumulate aluminum have also been used. Some mordants, and some dyes themselves, produce strong odors, and large-scale dyeworks were often isolated in their own districts.