Elementary entities in the context of "Complex (chemistry)"

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⭐ Core Definition: Elementary entities

In chemistry and physics, a molecular entity, or chemical entity, is "any constitutionally or isotopically distinct atom, molecule, ion, ion pair, radical, radical ion, complex, conformer, etc., identifiable as a separately distinguishable entity". A molecular entity is any singular entity, irrespective of its nature, used to concisely express any type of chemical particle that can exemplify some process: for example, atoms, molecules, ions, etc. can all undergo a chemical reaction.

Chemical species is the macroscopic equivalent of molecular entity and refers to sets or ensembles of molecular entities.

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Elementary entities in the context of Amount of substance

In chemistry, the amount of substance (symbol n) in a given sample of matter is defined as a ratio (n = N/NA) between the number of elementary entities (N) and the Avogadro constant (NA). The unit of amount of substance in the International System of Units is the mole (symbol: mol), a base unit. Since 2019, the mole has been defined such that the value of the Avogadro constant NA is exactly 6.02214076×10 mol, defining a macroscopic unit convenient for use in laboratory-scale chemistry. The elementary entities are usually molecules, atoms, ions, or ion pairs of a specified kind. The particular substance sampled may be specified using a subscript or in parentheses, e.g., the amount of sodium chloride (NaCl) could be denoted as nNaCl or n(NaCl). Sometimes, the amount of substance is referred to as the chemical amount or, informally, as the "number of moles" in a given sample of matter. The latter term is deprecated by the IUPAC because, for a substance X, the correct meaning of "number of moles" is n(X)/mol. The amount of substance in a sample can be calculated from measured quantities, such as mass or volume, given the molar mass of the substance or the molar volume of an ideal gas at a given temperature and pressure.

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