An electrochemical cell is a device that either generates electrical energy from chemical reactions in a so-called galvanic or voltaic cell, or induces chemical reactions (electrolysis) by applying external electrical energy in an electrolytic cell.
Both galvanic and electrolytic cells can be thought of as having two half-cells: consisting of separate oxidation and reduction reactions.
Direct current (DC) is one-directional flow of electric charge. An electrochemical cell is a prime example of DC power. Direct current may flow through a conductor such as a wire, but can also flow through semiconductors, insulators, or even through a vacuum as in electron or ion beams. The electric current flows in a constant direction, distinguishing it from alternating current (AC). A term formerly used for this type of current was galvanic current.
The abbreviations AC and DC are often used to mean simply alternating and direct, as when they modify current or voltage.
An electric battery is a source of electric power consisting of one or more electrochemical cells with external connections for powering electrical devices. When a battery is supplying power, its positive terminal is the cathode and its negative terminal is the anode. The terminal marked negative is the source of electrons. When a battery is connected to an external electric load, those negatively charged electrons flow through the circuit and reach the positive terminal, thus causing a redox reaction by attracting positively charged ions, or cations. Thus, higher energy reactants are converted to lower energy products, and the free-energy difference is delivered to the external circuit as electrical energy. Historically the term "battery" specifically referred to a device composed of multiple cells; however, the usage has evolved to include devices composed of a single cell.
Primary (single-use or "disposable") batteries are used once and discarded, as the electrode materials are irreversibly changed during discharge; a common example is the alkaline battery used for flashlights and a multitude of portable electronic devices. Secondary (rechargeable) batteries can be discharged and recharged multiple times using an applied electric current; the original composition of the electrodes can be restored by reverse current. Examples include the lead–acid batteries used in vehicles and lithium-ion batteries used for portable electronics such as laptops and mobile phones.
A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requiring a continuous source of fuel and oxygen (usually from air) to sustain the chemical reaction, whereas in a battery the chemical energy usually comes from substances that are already present in the battery. Fuel cells can produce electricity continuously for as long as fuel and oxygen are supplied.
The first fuel cells were invented by Sir William Grove in 1838. The first commercial use of fuel cells came almost a century later following the invention of the hydrogen–oxygen fuel cell by Francis Thomas Bacon in 1932. The alkaline fuel cell, also known as the Bacon fuel cell after its inventor, has been used in NASA space programs since the mid-1960s to generate power for satellites and space capsules. Since then, fuel cells have been used in many other applications. Fuel cells are used for primary and backup power for commercial, industrial and residential buildings and in remote or inaccessible areas. They are also used to power fuel cell vehicles, including forklifts, automobiles, buses, trains, boats, motorcycles, and submarines.
Electric field work is the work performed by an electric field on a charged particle in its vicinity. The work per unit of charge is defined as the movement of negligible test charge between two points, and is expressed as the difference in electric potential at those points. The work can be done, for example, by generators, (electrochemical cells) or thermocouples generating an electromotive force.
Electric field work is formally equivalent to work by other force fields in physics, and the formalism for electrical work is identical to that of mechanical work.
A rechargeable battery, storage battery, or secondary cell (formally a type of energy accumulator) is a type of electric battery which can be charged, discharged into a load, and recharged many times, as opposed to a disposable or primary battery, which is supplied fully charged and discarded after use. It is composed of one or more electrochemical cells. The term "accumulator" is used as it accumulates and stores energy through a reversible electrochemical reaction. Rechargeable batteries are produced in many different shapes and sizes, ranging from button cells to megawatt systems connected to stabilize an electrical distribution network. Several different combinations of electrode materials and electrolytes are used, including lead–acid, zinc–air, nickel–cadmium (NiCd), nickel–metal hydride (NiMH), lithium-ion (Li-ion), lithium iron phosphate (LiFePO4), and lithium-ion polymer (Li-ion polymer).
Rechargeable batteries typically initially cost more than disposable batteries but have a much lower total cost of ownership and environmental impact, as they can be recharged inexpensively many times before they need replacing. Some rechargeable battery types are available in the same sizes and voltages as disposable types, and can be used interchangeably with them. Billions of dollars in research are being invested around the world for improving batteries as industry focuses on building better batteries.
An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or a gas). In electrochemical cells, electrodes are essential parts that can consist of a variety of materials (chemicals) depending on the type of cell. An electrode may be called either a cathode or anode according to the direction of the electric current, unrelated to the potential difference between electrodes.
Michael Faraday coined the term "electrode" in 1833; the word recalls the Greek ἤλεκτρον (ḗlektron, "amber") and ὁδός (hodós, "path, way").
A flow battery, or redox flow battery (after reduction–oxidation), is a type of electrochemical cell where chemical energy is provided by two chemical components dissolved in liquids that are pumped through the system on separate sides of a membrane. Ion transfer inside the cell (accompanied by current flow through an external circuit) occurs across the membrane while the liquids circulate in their respective spaces.
A flow battery may be used like a fuel cell (where new charged negolyte (a.k.a. reducer or fuel) and charged posolyte (a.k.a. oxidant) are added to the system) or like a rechargeable battery (where an electric power source drives regeneration of the reducer and oxidant).