Dissociation (chemistry)

Hydroxide is a diatomic anion with chemical formula OH. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical.The corresponding electrically neutral compound HO is the hydroxyl radical. The corresponding covalently bound group −OH of atoms is the hydroxy group.Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry.

Many inorganic substances which bear the word hydroxide in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups.

Acid strength is the tendency of an acid, symbolised by the chemical formula HA, to dissociate into a proton, H, and an anion, A. The dissociation or ionization of a strong acid in solution is effectively complete, except in its most concentrated solutions.

Examples of strong acids are hydrochloric acid (HCl), perchloric acid (HClO₄), nitric acid (HNO₃) and sulfuric acid (H₂SO₄).

Atmospheric science is the study of the Earth's atmosphere and its various inner-working physical processes. Meteorology includes atmospheric chemistry and atmospheric physics with a major focus on weather forecasting. Climatology is the study of atmospheric conditions over timescales longer than those of weather, focusing on average climate conditions and their variability over time. Aeronomy is the study of the upper layers of the atmosphere, where dissociation and ionization are important. Atmospheric science has been extended to the field of planetary science and the study of the atmospheres of the planets and natural satellites of the Solar System.

Experimental instruments used in atmospheric science include satellites, rocketsondes, radiosondes, weather balloons, radars, and lasers.

Aeronomy is the scientific study of the upper atmosphere of the Earth and corresponding regions of the atmospheres of other planets. It is a branch of both atmospheric chemistry and atmospheric physics. Scientists specializing in aeronomy, known as aeronomers, study the motions and chemical composition and properties of the Earth's upper atmosphere and regions of the atmospheres of other planets that correspond to it, as well as the interaction between upper atmospheres and the space environment. In atmospheric regions aeronomers study, chemical dissociation and ionization are important phenomena.

In biochemistry and pharmacology, a ligand is a substance that forms a complex with a biomolecule to serve a biological purpose. The etymology stems from Latin ligare, which means 'to bind'. In protein-ligand binding, the ligand is usually a molecule which produces a signal by binding to a site on a target protein. The binding typically results in a change of conformational isomerism (conformation) of the target protein. In DNA-ligand binding studies, the ligand can be a small molecule, ion, or protein which binds to the DNA double helix. The relationship between ligand and binding partner is a function of charge, hydrophobicity, and molecular structure.

Binding occurs by intermolecular forces, such as ionic bonds, hydrogen bonds and Van der Waals forces. The association or docking is actually reversible through dissociation. Measurably irreversible covalent bonding between a ligand and target molecule is atypical in biological systems. In contrast to the definition of ligand in metalorganic and inorganic chemistry, in biochemistry it is ambiguous whether the ligand generally binds at a metal site, as is the case in hemoglobin. In general, the interpretation of ligand is contextual with regard to what sort of binding has been observed.

An elementary reaction is a chemical reaction in which one or more chemical species react directly to form products in a single reaction step and with a single transition state. In practice, a reaction is assumed to be elementary if no reaction intermediates have been detected or need to be postulated to describe the reaction on a molecular scale. An apparently elementary reaction may be in fact a stepwise reaction, i.e. a complicated sequence of chemical reactions, with reaction intermediates of variable lifetimes.

In a unimolecular elementary reaction, a molecule A dissociates or isomerises to form the products(s)

A rotaxane (from Latin rota 'wheel' and axis 'axle') is a mechanically interlocked molecular architecture consisting of a dumbbell-shaped molecule which is threaded through a macrocycle (see graphical representation). The two components of a rotaxane are kinetically trapped since the ends of the dumbbell (often called stoppers) are larger than the internal diameter of the ring and prevent dissociation (unthreading) of the components since this would require significant distortion of the covalent bonds.

Much of the research concerning rotaxanes and other mechanically interlocked molecular architectures, such as catenanes, has been focused on their efficient synthesis or their utilization as artificial molecular machines. However, examples of rotaxane substructure have been found in naturally occurring peptides, including: cystine knot peptides, cyclotides or lasso-peptides such as microcin J25.

The carbonic anhydrases (or carbonate dehydratases) (EC 4.2.1.1) form a family of enzymes that catalyze the interconversion between carbon dioxide and water and the dissociated ions of carbonic acid (i.e. bicarbonate and hydrogen ions). The active site of most carbonic anhydrases contains a zinc ion. They are therefore classified as metalloenzymes. The enzyme maintains acid-base balance and helps transport carbon dioxide.

Carbonic anhydrase helps maintain acid–base homeostasis, regulate pH, and fluid balance. Depending on its location, the role of the enzyme changes slightly. For example, carbonic anhydrase produces acid in the stomach lining. In the kidney, the control of bicarbonate ions influences the water content of the cell. The control of bicarbonate ions also influences the water content in the eyes. Inhibitors of carbonic anhydrase are used to treat glaucoma, the excessive build-up of water in the eyes. Blocking this enzyme shifts the fluid balance in the eyes to reduce fluid build-up thereby relieving pressure.

In aerodynamics, hypersonic speed refers to speeds much faster than the speed of sound, usually more than approximately Mach 5.

The precise Mach number at which a craft can be said to be flying at hypersonic speed varies, since individual physical changes in the airflow (like molecular dissociation and ionization) occur at different speeds; these effects collectively become important around Mach 5–10. The hypersonic regime can also be alternatively defined as speeds where specific heat capacity changes with the temperature of the flow as kinetic energy of the moving object is converted into heat.

In chemistry, bond cleavage, or bond fission, is the splitting of chemical bonds. This can be generally referred to as dissociation when a molecule is cleaved into two or more fragments.

In general, there are two classifications for bond cleavage: homolytic and heterolytic, depending on the nature of the process. The triplet and singlet excitation energies of a sigma bond can be used to determine if a bond will follow the homolytic or heterolytic pathway. A metal−metal sigma bond is an exception because the bond's excitation energy is extremely high, thus cannot be used for observation purposes.

Speleogenesis is the origin and development of caves, the primary process that determines essential features of the hydrogeology of karst and guides its evolution. It often deals with the development of caves through limestone, caused by the presence of water with carbon dioxide dissolved within it, producing carbonic acid which permits the dissociation of the calcium carbonate in the limestone.

In chemistry, dimerization is the process of joining two identical or similar molecular entities by bonds. The resulting bonds can be either strong or weak. Many symmetrical chemical species are described as dimers, even when the monomer is unknown or highly unstable.

The term homodimer is used when the two subunits are identical (e.g. A–A) and heterodimer when they are not (e.g. A–B). The reverse of dimerization is often called dissociation. When two oppositely-charged ions associate into dimers, they are referred to as Bjerrum pairs, after Danish chemist Niels Bjerrum.

In chemistry, an acid dissociation constant (also known as acidity constant, or acid-ionization constant; denoted ⁠${\displaystyle K_{a}}$⁠) is a quantitative measure of the strength of an acid in solution. It is the equilibrium constant for a chemical reaction

known as dissociation in the context of acid–base reactions. The chemical species HA is an acid that dissociates into A, called the conjugate base of the acid, and a hydrogen ion, H. The system is said to be in equilibrium when the concentrations of its components do not change over time, because both forward and backward reactions are occurring at the same rate.