Diamagnetism in the context of "Quantum mechanical"

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⭐ Core Definition: Diamagnetism

Diamagnetism is the property of materials that are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracted by a magnetic field. Diamagnetism is a quantum mechanical effect that occurs in all materials; when it is the only contribution to the magnetism, the material is called diamagnetic. In paramagnetic and ferromagnetic substances, the weak diamagnetic force is overcome by the attractive force of magnetic dipoles in the material. The magnetic permeability of diamagnetic materials is less than the permeability of vacuum, μ0. In most materials, diamagnetism is a weak effect which can be detected only by sensitive laboratory instruments, but a superconductor acts as a strong diamagnet because it entirely expels any magnetic field from its interior (the Meissner effect).

Diamagnetism was first discovered when Anton Brugmans observed in 1778 that bismuth was repelled by magnetic fields. In 1845, Michael Faraday demonstrated that it was a property of matter and concluded that every material responded (in either a diamagnetic or paramagnetic way) to an applied magnetic field. On a suggestion by William Whewell, Faraday first referred to the phenomenon as diamagnetic (the prefix dia- meaning through or across), then later changed it to diamagnetism.

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Diamagnetism in the context of Ozone

Ozone (/ˈzn/ ), also called trioxygen, is an inorganic molecule with the chemical formula O
3
. It is a pale-blue gas with a distinctively pungent odour. It is an allotrope of oxygen that is much less stable than the diatomic allotrope O
2
, breaking down in the lower atmosphere to O
2
(dioxygen). Ozone is formed from dioxygen by the action of ultraviolet (UV) light and electrical discharges within the Earth's atmosphere. It is present in very low concentrations throughout the atmosphere, with its highest concentration high in the ozone layer of the stratosphere, which absorbs most of the Sun's ultraviolet (UV) radiation.

Ozone's odour is reminiscent of chlorine, and detectable by many people at concentrations of as little as 0.1 ppm in air. Ozone's O3 structure was determined in 1865. The molecule was later proven to have a bent structure and to be weakly diamagnetic. At standard temperature and pressure, ozone is a pale blue gas that condenses at cryogenic temperatures to a dark blue liquid and finally a violet-black solid. Ozone's instability with regard to more common dioxygen is such that both concentrated gas and liquid ozone may decompose explosively at elevated temperatures, physical shock, or fast warming to the boiling point. It is therefore used commercially only in low concentrations.

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Diamagnetism in the context of Magnetic field

A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to the magnetic field. A permanent magnet's magnetic field pulls on ferromagnetic materials such as iron, and attracts or repels other magnets. In addition, a nonuniform magnetic field exerts minuscule forces on "nonmagnetic" materials by three other magnetic effects: paramagnetism, diamagnetism, and antiferromagnetism, although these forces are usually so small they can only be detected by laboratory equipment. Magnetic fields surround magnetized materials, electric currents, and electric fields varying in time. Since both strength and direction of a magnetic field may vary with location, it is described mathematically by a function assigning a vector to each point of space, called a vector field (more precisely, a pseudovector field).

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Diamagnetism in the context of Bismuth

Bismuth is a chemical element; it has symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly iridescent appearance due to thin-film interference. Bismuth is both the most diamagnetic element and one of the least thermally conductive metals known.

Bismuth was formerly understood to be the element with the highest atomic mass whose nuclei do not spontaneously decay. However, in 2003 it was found to be very slightly radioactive. The metal's only primordial isotope, bismuth-209, undergoes alpha decay with a half-life roughly a billion times longer than the estimated age of the universe.

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Diamagnetism in the context of Michael Faraday

Michael Faraday (UK: /ˈfærəˌd/ FAR-uh-day, US: /ˈfærədi/ FAR-uh-dee; 22 September 1791 – 25 August 1867) was an English chemist and physicist who contributed to the study of electrochemistry and electromagnetism. His main discoveries include the principles underlying electromagnetic induction, diamagnetism, and electrolysis. Although Faraday received little formal education, as a self-made man, he was one of the most influential scientists in history. It was by his research on the magnetic field around a conductor carrying a direct current that Faraday established the concept of the electromagnetic field in physics. Faraday also established that magnetism could affect rays of light and that there was an underlying relationship between the two phenomena. He similarly discovered the principles of electromagnetic induction, diamagnetism, and the laws of electrolysis. His inventions of electromagnetic rotary devices formed the foundation of electric motor technology, and it was largely due to his efforts that electricity became practical for use in technology. The SI unit of capacitance, the farad, is named after him.

As a chemist, Faraday discovered benzene and carbon tetrachloride, investigated the clathrate hydrate of chlorine, invented an early form of the Bunsen burner and the system of oxidation numbers, and popularised terminology such as "anode", "cathode", "electrode" and "ion". Faraday ultimately became the first and foremost Fullerian Professor of Chemistry at the Royal Institution, a lifetime position.

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Diamagnetism in the context of Lev Landau

Lev Davidovich Landau (Russian: Лев Дави́дович Ланда́у; 22 January 1908 – 1 April 1968) was a Soviet physicist who made fundamental contributions to many areas of theoretical physics. He was considered as one of the last scientists who were universally well-versed and made seminal contributions to all branches of physics. He is credited with laying the foundations of twentieth century condensed matter physics, and is also considered arguably the greatest Soviet theoretical physicist.

His accomplishments include the independent co-discovery of the density matrix method in quantum mechanics (alongside John von Neumann), the quantum mechanical theory of diamagnetism, the theory of superfluidity, the theory of second-order phase transitions, invention of order parameter technique, the Ginzburg–Landau theory of superconductivity, the theory of Fermi liquids, the explanation of Landau damping in plasma physics, the Landau pole in quantum electrodynamics, the two-component theory of neutrinos, and Landau's equations for S-matrix singularities. He received the 1962 Nobel Prize in Physics for his development of a mathematical theory of superfluidity that accounts for the properties of liquid helium II at a temperature below 2.17 K (−270.98 °C).

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Diamagnetism in the context of Paramagnetism

Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, diamagnetic materials are repelled by magnetic fields and form induced magnetic fields in the direction opposite to that of the applied magnetic field. Paramagnetic materials include most chemical elements and some compounds; they have a relative magnetic permeability slightly greater than 1 (i.e., a small positive magnetic susceptibility) and hence are attracted to magnetic fields. The magnetic moment induced by the applied field is linear in the field strength and rather weak. It typically requires a sensitive analytical balance to detect the effect and modern measurements on paramagnetic materials are often conducted with a SQUID magnetometer.

Paramagnetism is due to the presence of unpaired electrons in the material, so most atoms with incompletely filled atomic orbitals are paramagnetic, although exceptions such as copper exist. Due to their spin, unpaired electrons have a magnetic dipole moment and act like tiny magnets. An external magnetic field causes the electrons' spins to align parallel to the field, causing a net attraction. Paramagnetic materials include aluminium, oxygen, titanium, and iron oxide (FeO). Therefore, a simple rule of thumb is used in chemistry to determine whether a particle (atom, ion, or molecule) is paramagnetic or diamagnetic: if all electrons in the particle are paired, then the substance made of this particle is diamagnetic; if it has unpaired electrons, then the substance is paramagnetic.

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Diamagnetism in the context of John Tyndall

John Tyndall (/ˈtɪndəl/; 2 August 1820 – 4 December 1893) was an Irish physicist. His scientific fame arose in the 1850s from his study of diamagnetism. Later he made discoveries in the realms of infrared radiation and the physical properties of air, proving the connection between atmospheric CO2 and what is now known as the greenhouse effect in 1859.

Tyndall also published more than a dozen science books which brought state-of-the-art 19th century experimental physics to a wide audience. From 1853 to 1887 he was professor of physics at the Royal Institution of Great Britain in London. He was elected as a member to the American Philosophical Society in 1868.

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