Diamagnetic in the context of Pyrolytic carbon


Diamagnetic in the context of Pyrolytic carbon

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⭐ Core Definition: Diamagnetic

Diamagnetism is the property of materials that are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracted by a magnetic field. Diamagnetism is a quantum mechanical effect that occurs in all materials; when it is the only contribution to the magnetism, the material is called diamagnetic. In paramagnetic and ferromagnetic substances, the weak diamagnetic force is overcome by the attractive force of magnetic dipoles in the material. The magnetic permeability of diamagnetic materials is less than the permeability of vacuum, μ0. In most materials, diamagnetism is a weak effect which can be detected only by sensitive laboratory instruments, but a superconductor acts as a strong diamagnet because it entirely expels any magnetic field from its interior (the Meissner effect).

Diamagnetism was first discovered when Anton Brugmans observed in 1778 that bismuth was repelled by magnetic fields. In 1845, Michael Faraday demonstrated that it was a property of matter and concluded that every material responded (in either a diamagnetic or paramagnetic way) to an applied magnetic field. On a suggestion by William Whewell, Faraday first referred to the phenomenon as diamagnetic (the prefix dia- meaning through or across), then later changed it to diamagnetism.

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Diamagnetic in the context of Tin(IV) oxide

Tin(IV) oxide, also known as stannic oxide, is the inorganic compound with the formula SnO2. The mineral form of SnO2 is called cassiterite, and this is the main ore of tin. With many other names, this oxide of tin is an important material in tin chemistry. It is a colourless, diamagnetic, amphoteric solid.

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Diamagnetic in the context of Zirconocene dichloride

Zirconocene dichloride is an organozirconium compound composed of a zirconium central atom, with two cyclopentadienyl and two chloro ligands. It is a colourless diamagnetic solid that is somewhat stable in air.

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Diamagnetic in the context of Ferrocyanide

Ferrocyanide is the anion [Fe(CN)6]. Salts of this coordination complex give yellow solutions. It is usually available as the salt potassium ferrocyanide, which has the formula K4Fe(CN)6. [Fe(CN)6] is a diamagnetic species, featuring low-spin iron(II) center in an octahedral ligand environment. Although many salts of cyanide are highly toxic, ferro- and ferricyanides are less toxic because they tend not to release free cyanide. It is of commercial interest as a precursor to the pigment Prussian blue and, as its potassium salt, an anticaking agent.

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Diamagnetic in the context of Magnetic domains

A magnetic domain is a region within a magnetic material in which the magnetization is in a uniform direction. This means that the individual magnetic moments of the atoms are aligned with one another and they point in the same direction. When cooled below a temperature called the Curie temperature, the magnetization of a piece of ferromagnetic material spontaneously divides into many small regions called magnetic domains. The magnetization within each domain points in a uniform direction, but the magnetization of different domains may point in different directions. Magnetic domain structure is responsible for the magnetic behavior of ferromagnetic materials like iron, nickel, cobalt and their alloys, and ferrimagnetic materials like ferrite. This includes the formation of permanent magnets and the attraction of ferromagnetic materials to a magnetic field. The regions separating magnetic domains are called domain walls, where the magnetization rotates coherently from the direction in one domain to that in the next domain. The study of magnetic domains is called micromagnetics.

Magnetic domains form in materials which have magnetic ordering; that is, their dipoles spontaneously align due to the exchange interaction. These are the ferromagnetic, ferrimagnetic and antiferromagnetic materials. Paramagnetic and diamagnetic materials, in which the dipoles align in response to an external field but do not spontaneously align, do not have magnetic domains.

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