Cyanoacetylene in the context of Comet Hale–Bopp


Cyanoacetylene in the context of Comet Hale–Bopp

⭐ Core Definition: Cyanoacetylene

Cyanoacetylene is an organic compound with the formula C3HN or H−C≡C−C≡N. It is the simplest cyanopolyyne. Cyanoacetylene has been detected by spectroscopic methods in interstellar clouds, in the coma of comet Hale–Bopp and in the atmosphere of Saturn's moon Titan, where it sometimes forms expansive fog-like clouds.

Cyanoacetylene is one of the molecules that was produced in the Miller–Urey experiment.

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Cyanoacetylene in the context of Atmosphere of Titan

The atmosphere of Titan is the dense layer of gases surrounding Titan, the largest moon of Saturn. Titan is the only natural satellite of a planet in the Solar System with an atmosphere that is denser than the atmosphere of Earth and is one of two moons with an atmosphere significant enough to drive weather (the other being the atmosphere of Triton). Titan's lower atmosphere is primarily composed of nitrogen (94.2%), methane (5.65%), and hydrogen (0.099%). There are trace amounts of other hydrocarbons, such as ethane, diacetylene, methylacetylene, acetylene, propane, PAHs and of other gases, such as cyanoacetylene, hydrogen cyanide, carbon dioxide, carbon monoxide, cyanogen, acetonitrile, argon and helium. The isotopic study of nitrogen isotopes ratio also suggests acetonitrile may be present in quantities exceeding hydrogen cyanide and cyanoacetylene. The surface pressure is about 50% higher than on Earth at 1.5 bars (147 kPa). This is higher than the pressure at the triple point of methane, which allows there to be liquid methane on the surface in addition to the gaseous methane in the atmosphere. The orange color as seen from space is produced by other more complex chemicals in small quantities, possibly tholins, tar-like organic precipitates.

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Cyanoacetylene in the context of Cyanopolyyne

In organic chemistry, cyanopolyynes are a family of organic compounds with the chemical formula HCnN (n = 3,5,7,…) and the structural formula H−[C≡C−]nC≡N (n = 1,2,3,…). Structurally, they are polyynes with a cyano group (−C≡N) covalently bonded to one of the terminal acetylene units (H−C≡C).

A rarely seen group of molecules both due to the difficulty in production and the unstable nature of the paired groups, the cyanopolyynes have been observed as a major organic component in interstellar clouds. This is believed to be due to the hydrogen scarcity of some of these clouds. Interference with hydrogen is one of the reasons for the molecule's instability due to the energetically favorable dissociation back into hydrogen cyanide and acetylene.

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