The cyano radical (or cyanido radical) is a radical with molecular formula CN, sometimes written CN. The cyano radical was one of the first detected molecules in the interstellar medium, in 1938. Its detection and analysis was influential in astrochemistry. The discovery was confirmed with a coudé spectrograph, which was made famous and credible due to this detection. ·CN has been observed in both diffuse clouds and dense clouds. Usually, CN is detected in regions with hydrogen cyanide, hydrogen isocyanide, and HCNH, since it is involved in the creation and destruction of these species (see also Cyanogen).
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Cyano radical in the context of Discovery of cosmic microwave background radiation
The discovery of cosmic microwave background radiation constitutes a major development in modern physical cosmology. In 1964, American physicist Arno Allan Penzias and radio-astronomer Robert Woodrow Wilson discovered the cosmic microwave background (CMB), estimating its temperature as 3.5 K, as they experimented with the Holmdel Horn Antenna. The new measurements were accepted as important evidence for a hot early Universe (Big Bang theory) and as evidence against the rival steady state theory as theoretical work around 1950 showed the need for a CMB for consistency with the simplest relativistic universe models. In 1978, Penzias and Wilson were awarded the Nobel Prize for Physics for their joint measurement. There had been a prior measurement of the cosmic background radiation (CMB) by Andrew McKellar in 1941 at an effective temperature of 2.3 K using CN stellar absorption lines observed by W. S. Adams. Although no reference to the CMB is made by McKellar, it was not until much later after the Penzias and Wilson measurements, that the significance of this earlier measurement was understood.
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Cyanogen is the chemical compound with the formula (CN)2. Its structure is N≡C−C≡N. The simplest stable carbon nitride, it is a colorless and highly toxic gas with a pungent odor. The molecule is a pseudohalogen. Cyanogen molecules are linear, and consist of two CN groups ‒ analogous to diatomic halogen molecules, such as Cl2, but far less oxidizing. The two cyano groups are bonded together at their carbon atoms, though other isomers have been detected. The name is also used for the CN radical, and hence is used for compounds such as cyanogen bromide (Br−C≡N) (but see also Cyano radical). When burned at increased pressure with oxygen, it is possible to get a blue tinted flame, the temperature of which is about 4,800 °C (8,670 °F) (a higher temperature is possible with ozone). It is as such regarded as the gas with the second highest temperature of burning (after dicyanoacetylene).
Cyanogen is the anhydride of oxamide:
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