Critical mass (nuclear) in the context of Isotope separation

Gun-type fission weapons are fission-based nuclear weapons whose design assembles their fissile material into a supercritical mass by the use of the "gun" method: shooting one piece of sub-critical material into another. Although this is sometimes pictured as two sub-critical hemispheres driven together to make a supercritical sphere, typically a hollow projectile is shot onto a cylindrical spike, which fills the hole in its center. Its name is a reference to the fact that it is shooting the material through an artillery barrel as if it were a projectile. Developed and deployed by the Manhattan Project, gun-type designs were quickly replaced by the more efficient implosion-type weapons.

All known gun-type fission weapons have used highly enriched uranium (HEU). The high spontaneous fission rates of plutonium isotopes make it very impractical for use in gun-type designs, as in the abandoned Thin Man design. Additionally, the efficiency is low, increasing the amount of HEU required and weapon weight. The main reason for this is the fissile material does not undergo compression (and resulting density increase) as does the implosion design. Instead, gun-type bombs assemble the supercritical mass by amassing such a large quantity of uranium that the overall distance through which daughter neutrons must travel has so many mean free paths it becomes very probable most neutrons will find uranium nuclei to collide with, before escaping the supercritical mass. HEU could be more efficiently used by the composite cores of early implosion-type weapons.

A criticality accident is an accidental uncontrolled nuclear fission chain reaction. It is sometimes referred to as a critical excursion, critical power excursion, divergent chain reaction, or simply critical. Any such event involves the unintended accumulation or arrangement of a critical mass of fissile material, for example enriched uranium or plutonium. Criticality accidents can release potentially fatal radiation doses if they occur in an unprotected environment.

Under normal circumstances, a critical or supercritical fission reaction (one that is self-sustaining in power or increasing in power) should only occur inside a safely shielded location, such as a reactor core or a suitable test environment. A criticality accident occurs if the same reaction is achieved unintentionally, for example in an unsafe environment or during reactor maintenance.