Copolyester in the context of Polyethylene terephthalate


Copolyester in the context of Polyethylene terephthalate

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⭐ Core Definition: Copolyester

A copolyester is a copolymer synthesized by modification of polyesters, which are combinations of diacids and diols. For example, by introducing other diacids, such as isophthalic acid (IPA), or other diols, such as cyclohexane dimethanol (CHDM) to the polyester polyethylene terephthalate (PET), the material becomes a copolyester due to its comonomer content.

Copolyesters retain their strength, clarity, and other mechanical properties even when exposed to a variety of chemicals that typically affect other materials, such as polycarbonates. This, plus their versatility and flexibility, allows manufacturers to use them effectively in the design of both high-volume, low-cost parts as well as critical, more expensive component parts.

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Copolyester in the context of Heteropolymer

In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are sometimes called bipolymers. Those obtained from three and four monomers are called terpolymers and quaterpolymers, respectively. Copolymers can be characterized by a variety of techniques such as NMR spectroscopy and size-exclusion chromatography to determine the molecular size, weight, properties, and composition of the material.

Commercial copolymers include acrylonitrile butadiene styrene (ABS), styrene/butadiene co-polymer (SBR), nitrile rubber, styrene-acrylonitrile, styrene-isoprene-styrene (SIS) and ethylene-vinyl acetate, all of which are formed by chain-growth polymerization. Another production mechanism is step-growth polymerization, which is used to produce the nylon-12/6/66 copolymer of nylon 12, nylon 6 and nylon 66, as well as the copolyester family. Copolymers can be used to develop commercial goods or drug delivery vehicles.

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