Cold finger in the context of "Condenser (heat transfer)"

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⭐ Core Definition: Cold finger

A cold finger is a piece of laboratory equipment that is used to generate a localized cold surface. It is named for its resemblance to a finger and is a type of cold trap. The device usually consists of a chamber that a coolant fluid (cold tap water, or perhaps something colder) can enter and leave. Another version involves filling the device with a cold material (examples: ice, dry ice or a mixture such as dry ice/acetone or ice/water).

Typically a cold finger is used in a sublimation apparatus, or can be used as a compact version of a condenser in either reflux reaction or distillation apparatus. Many commercially available rotary evaporators can be purchased with a cold finger in place of a Dimroth condenser, for example. When used as a condenser in a rotary evaporator, cold fingers can be cooled to a lower temperature of −78 °C (dry ice), compared with water condensers that can be cooled to −40 °C (ethylene glycol/water mixture). The lower temperature achieved reduces the quantity of volatile material exhausted into the air.

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Cold finger in the context of Sublimation (phase transition)

Sublimation is the transition of a substance directly from the solid to the gas state, without passing through the liquid state. The verb form of sublimation is sublime, or less preferably, sublimate. Sublimate also refers to the product obtained by sublimation. The point at which sublimation occurs rapidly (for further details, see below) is called critical sublimation point, or simply sublimation point. Notable examples include sublimation of dry ice at room temperature and atmospheric pressure, and that of solid iodine with heating.

The reverse process of sublimation is deposition (also called desublimation), in which a substance passes directly from a gas to a solid phase, without passing through the liquid state.

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