Carbon disulfide in the context of Thiocarbonic acid


Carbon disulfide in the context of Thiocarbonic acid

⭐ Core Definition: Carbon disulfide

Carbon disulfide (also spelled as carbon disulphide) is an inorganic compound with the chemical formula CS2 and structure S=C=S. It is also considered as the anhydride of thiocarbonic acid. It is a colorless, flammable, neurotoxic liquid that is used as a building block in organic synthesis. Pure carbon disulfide has a pleasant, ether- or chloroform-like odor, but commercial samples are usually yellowish and are typically contaminated with foul-smelling impurities.

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Carbon disulfide in the context of White phosphorus

White phosphorus, yellow phosphorus, or simply tetraphosphorus (P4) is an allotrope of phosphorus. It is a translucent waxy solid that quickly yellows in light (due to its photochemical conversion into red phosphorus), and impure white phosphorus is for this reason called yellow phosphorus. White phosphorus is the first allotrope of phosphorus, and was discovered in 1669 by Henning Brand.

When in an oxygen-containing atmosphere, it will exhibit a faint green glow in the absence of light. White phosphorus is also highly flammable and pyrophoric (self-igniting) upon contact with air. It is toxic, causing severe liver damage upon ingestion and phossy jaw from chronic ingestion or inhalation. The combustion of this form has a characteristic garlic odor, and samples are commonly coated with white "diphosphorus pentoxide", which consists of P4O10 tetrahedra with oxygen inserted between the phosphorus atoms and at their vertices. White phosphorus is only slightly soluble in water and can be stored under water. P4 is soluble in benzene, oils, carbon disulfide, and disulfur dichloride.

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Carbon disulfide in the context of Carbonyl sulfide

Carbonyl sulfide is the chemical compound with the linear formula O=C=S. It is a colorless flammable gas with an unpleasant odor. It is a linear molecule consisting of a carbonyl double bonded to a sulfur atom. Carbonyl sulfide can be considered to be intermediate between carbon dioxide and carbon disulfide, both of which are valence isoelectronic with it.

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Carbon disulfide in the context of Lyocell

Lyocell is a semi-synthetic fibre used to make textiles for clothing and other purposes. It is a form of regenerated cellulose made by dissolving pulp and dry jet-wet spinning. Unlike rayon, which is made by the more common viscose processes, Lyocell production does not use carbon disulfide, which is toxic to workers and the environment. Lyocell was originally trademarked as Tencel in 1992.

"Lyocell" has become a genericised trademark used to refer to the Lyocell process for making cellulose fibres. The United States Federal Trade Commission defines Lyocell as "a fiber composed of cellulose precipitated from an organic solution in which no substitution of the hydroxy groups takes place, and no chemical intermediates are formed". It classifies the fibre as a sub-category of rayon.

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Carbon disulfide in the context of Thiobacillus

Thiobacillus is a genus of Gram-negative Betaproteobacteria. Thiobacillus thioparus is the type species of the genus, and the type strain thereof is the Starkey strain, isolated by Robert Starkey in the 1930s from a field at Rutgers University in the United States of America. While over 30 "species" have been named in this genus since it was defined by Martinus Beijerinck in 1904, (the first strain was observed by the biological oceanographer Alexander Nathansohn in 1902 - likely what we would now call Halothiobacillus neapolitanus), most names were never validly or effectively published. The remainder were either reclassified into Paracoccus, Starkeya (both in the Alphaproteobacteria); Sulfuriferula, Annwoodia, Thiomonas (in the Betaproteobacteria); Halothiobacillus, Guyparkeria (in the Gammaproteobacteria), or Thermithiobacillus or Acidithiobacillus (in the Acidithiobacillia). The very loosely defined "species" Thiobacillus trautweinii was where sulfur oxidising heterotrophs and chemolithoheterotrophs were assigned in the 1910-1960s era, most of which were probably Pseudomonas species. Many species named in this genus were never deposited in service collections and have been lost.

All species are obligate autotrophs (using the transaldolase form of the Calvin-Benson-Bassham cycle) using elementary sulfur, thiosulfate, or polythionates as energy sources - the former Thiobacillus aquaesulis can grow weakly on complex media as a heterotroph, but has been reclassified to Annwoodia aquaesulis. Some strains (E6 and Tk-m) of the type species Thiobacillus thioparus can use the sulfur from dimethylsulfide, dimethyldisulfide, or carbon disulfide to support autotrophic growth - they oxidise the carbon from these species into carbon dioxide and assimilate it. Sulfur oxidation is achieved via the Kelly-Trudinger pathway.

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