Byproduct in the context of "Oil refinery"

Photoautotrophs are organisms that can utilize light energy from sunlight, and elements (such as carbon) from inorganic compounds, to produce organic materials needed to sustain their own metabolism (i.e. autotrophy). Such biological activities are known as photosynthesis, and examples of such organisms include plants, algae and cyanobacteria.

Eukaryotic photoautotrophs absorb photonic energy through the photopigment chlorophyll (a porphyrin derivative) in their endosymbiont chloroplasts, while prokaryotic photoautotrophs use chlorophylls and bacteriochlorophylls present in free-floating cytoplasmic thylakoids. Plants, algae, and cyanobacteria perform oxygenic photosynthesis that produces oxygen as a byproduct, while some bacteria perform anoxygenic photosynthesis.

Photosynthesis (/ˌfoʊtəˈsɪnθəsɪs/ FOH-tə-SINTH-ə-sis) is a system of biological processes by which photopigment-bearing autotrophic organisms, such as most plants, algae and cyanobacteria, convert light energy — typically from sunlight — into the chemical energy necessary to fuel their metabolism. The term photosynthesis usually refers to oxygenic photosynthesis, a process that releases oxygen as a byproduct of water splitting. Photosynthetic organisms store the converted chemical energy within the bonds of intracellular organic compounds (complex compounds containing carbon), typically carbohydrates like sugars (mainly glucose, fructose and sucrose), starches, phytoglycogen and cellulose. When needing to use this stored energy, an organism's cells then metabolize the organic compounds through cellular respiration. Photosynthesis plays a critical role in producing and maintaining the oxygen content of the Earth's atmosphere, and it supplies most of the biological energy necessary for complex life on Earth.

Some organisms also perform anoxygenic photosynthesis, which does not produce oxygen. Some bacteria (e.g. purple bacteria) uses bacteriochlorophyll to split hydrogen sulfide as a reductant instead of water, releasing sulfur instead of oxygen, which was a dominant form of photosynthesis in the euxinic Canfield oceans during the Boring Billion. Archaea such as Halobacterium also perform a type of non-carbon-fixing anoxygenic photosynthesis, where the simpler photopigment retinal and its microbial rhodopsin derivatives are used to absorb green light and produce a proton (hydron) gradient across the cell membrane, and the subsequent ion movement powers transmembrane proton pumps to directly synthesize adenosine triphosphate (ATP), the "energy currency" of cells. Such archaeal photosynthesis might have been the earliest form of photosynthesis that evolved on Earth, as far back as the Paleoarchean, preceding that of cyanobacteria (see Purple Earth hypothesis).

Cyanobacteria (/saɪˌænoʊbækˈtɪəriə/ sy-AN-oh-bak-TEER-ee-ə) are a group of autotrophic gram-negative bacteria of the phylum Cyanobacteriota that can obtain biological energy via oxygenic photosynthesis. The name "cyanobacteria" (from Ancient Greek κύανος (kúanos) 'blue') refers to their bluish green (cyan) color, which forms the basis of cyanobacteria's informal common name, blue-green algae.

Cyanobacteria are probably the most numerous taxon to have ever existed on Earth and the first organisms known to have produced oxygen, having appeared in the middle Archean eon and apparently originated in a freshwater or terrestrial environment. Their photopigments can absorb the red- and blue-spectrum frequencies of sunlight (thus reflecting a greenish color) to split water molecules into hydrogen ions and oxygen. The hydrogen ions are used to react with carbon dioxide to produce complex organic compounds such as carbohydrates (a process known as carbon fixation), and the oxygen is released as a byproduct. By continuously producing and releasing oxygen over billions of years, cyanobacteria are thought to have converted the early Earth's anoxic, weakly reducing prebiotic atmosphere, into an oxidizing one with free gaseous oxygen (which previously would have been immediately removed by various surface reductants), resulting in the Great Oxidation Event and the "rusting of the Earth" during the early Proterozoic, dramatically changing the composition of life forms on Earth. The subsequent adaptation of early single-celled organisms to survive in oxygenous environments likely led to endosymbiosis between anaerobes and aerobes, and hence the evolution of eukaryotes during the Paleoproterozoic.

Bacteriochlorophylls (BChl) are photosynthetic pigments that occur in various phototrophic bacteria. They were discovered by C. B. van Niel in 1932. They are related to chlorophylls, which are the primary pigments in plants, algae, and cyanobacteria. Organisms that contain bacteriochlorophyll conduct photosynthesis to sustain their energy requirements, but the process is anoxygenic and does not produce oxygen as a byproduct. They use wavelengths of light not absorbed by plants or cyanobacteria. Replacement of Mg with protons gives bacteriophaeophytin (BPh), the phaeophytin form.

• Structures of major bacteriochlorophylls
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  bacteriochlorophyll a
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  bacteriochlorophyll b
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  bacteriochlorophyll c
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  bacteriochlorophyll d
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  bacteriochlorophyll e
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  bacteriochlorophyll f
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  bacteriochlorophyll g

Anoxygenic photosynthesis is a special form of photosynthesis used by some bacteria and archaea, which differs from the better known oxygenic photosynthesis in plants and cyanobacteria in the reductant used (e.g. hydrogen sulfide instead of water) and the byproduct generated (e.g. elemental sulfur instead of molecular oxygen).

Unlike oxygenic phototrophs that only use the Calvin cycle to fix carbon dioxide, anoxygenic phototrophs can use both the Calvin cycle and the reverse TCA cycle to fix carbon dioxide. Additionally, unlike its oxygenic counterpart that predominantly uses chlorophyll, this type of photosynthesis uses the bacteriochlorophyll (BChl) to utilize light as an energy source. A precursor to oxygenic photosynthesis but having been developed after chemolithoautotrophy, anoxygenic photosynthesis uses one of two reaction centers while oxygenic photosynthesis uses both type I and type II reaction centers.

Selenium is a chemical element; it has symbol Se and atomic number 34. It has various physical appearances, including a brick-red powder, a vitreous black solid, and a grey metallic-looking form. It seldom occurs in this elemental state or as pure ore compounds in Earth's crust. Selenium (from σελήνη 'moon') was discovered in 1817 by Jöns Jacob Berzelius, who noted the similarity of the new element to the previously discovered tellurium (named for the Earth).

Selenium is found in metal sulfide ores, where it substitutes for sulfur. Commercially, selenium is produced as a byproduct in the refining of these ores. Minerals that are pure selenide or selenate compounds are rare. The chief commercial uses for selenium today are glassmaking and pigments. Selenium is a semiconductor and is used in photocells. Applications in electronics, once important, have been mostly replaced with silicon semiconductor devices. Selenium is still used in a few types of DC power surge protectors and one type of fluorescent quantum dot.