Birefringence in the context of "Mechanical stress"

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⭐ Core Definition: Birefringence

Birefringence, also called double refraction, is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are described as birefringent or birefractive. The birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress.

Birefringence is responsible for the phenomenon of double refraction whereby a ray of light, when incident upon a birefringent material, is split by polarization into two rays taking slightly different paths. This effect was first described by Danish scientist Rasmus Bartholin in 1669, who observed it in Iceland spar (calcite) crystals which have one of the strongest birefringences. In the 19th century Augustin-Jean Fresnel described the phenomenon in terms of polarization, understanding light as a wave with field components in transverse polarization (perpendicular to the direction of the wave vector).

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Birefringence in the context of Cinnabar

Cinnabar (/ˈsɪnəˌbɑːr/; from Ancient Greek κιννάβαρι (kinnábari)), also called cinnabarite (/ˌsɪnəˈbɑːrt/) or mercurblende, is the bright scarlet to brick-red form of mercury(II) sulfide (HgS). It is the most common source ore for refining elemental mercury and is the historic source for the brilliant red or scarlet pigment termed vermilion and associated red mercury pigments.

Cinnabar generally occurs as a vein-filling mineral associated with volcanic activity and alkaline hot springs. The mineral resembles quartz in symmetry and it exhibits birefringence. Cinnabar has a mean refractive index near 3.2, a hardness between 2.0 and 2.5, and a specific gravity of approximately 8.1. The color and properties derive from a structure that is a hexagonal crystalline lattice belonging to the trigonal crystal system, crystals that sometimes exhibit twinning.

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Birefringence in the context of Optical properties

The optical properties of a material define how it interacts with light. The optical properties of matter are studied in optical physics (a subfield of optics) and applied in materials science. The optical properties of matter include:

A basic distinction is between isotropic materials, which exhibit the same properties regardless of the direction of the light, and anisotropic ones, which exhibit different properties when light passes through them in different directions.

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Birefringence in the context of Polarized light microscopy

Polarized light microscopy can mean any of a number of optical microscopy techniques involving polarized light. Simple techniques include illumination of the sample with polarized light. Directly transmitted light can, optionally, be blocked with a polariser oriented at 90 degrees to the illumination. More complex microscopy techniques which take advantage of polarized light include differential interference contrast microscopy and interference reflection microscopy. Scientists will often use a device called a polarizing plate to convert natural light into polarized light.

These illumination techniques are most commonly used on birefringent samples where the polarized light interacts strongly with the sample and so generating contrast with the background. Polarized light microscopy is used extensively in optical mineralogy.

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Birefringence in the context of Muscovite

Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(AlSi3O10)(F,OH)2, or (KF)2(Al2O3)3(SiO2)6(H2O). It has a highly perfect basal cleavage yielding remarkably thin laminae (sheets) which are often highly elastic. Sheets of muscovite 5 by 3 meters (16.4 ft × 9.8 ft) have been found in Nellore, India.

Muscovite has a Mohs hardness of 2–2.25 parallel to the [001] face, 4 perpendicular to the [001] and a specific gravity of 2.76–3. It can be colorless or tinted through grays, violet or red, and can be transparent or translucent. It is anisotropic and has high birefringence. Its crystal system is monoclinic. The green, chromium-rich variety is called fuchsite; mariposite is also a chromium-rich type of muscovite.

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Birefringence in the context of Anatase

Anatase is a metastable mineral form of titanium dioxide (TiO2) with a tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other polymorphs (or mineral forms) of titanium dioxide are known to occur naturally: brookite, akaogiite, and rutile, with rutile being the most common and most stable of the bunch. Anatase is formed at relatively low temperatures and found in minor concentrations in igneous and metamorphic rocks. Glass coated with a thin film of TiO2 shows antifogging and self-cleaning properties under ultraviolet radiation.

Anatase is always found as small, isolated, and sharply developed crystals, and like rutile, it crystallizes in a tetragonal system. Anatase is metastable at all temperatures and pressures, with rutile being the equilibrium polymorph. Nevertheless, anatase is often the first titanium dioxide phase to form in many processes due to its lower surface energy, with a transformation to rutile taking place at elevated temperatures. Although the degree of symmetry is the same for both anatase and rutile phases, there is no relation between the interfacial angles of the two minerals, except in the prism-zone of 45° and 90°. The common octahedral crystal habit of anatase, with four perfect cleavage planes, has an angle over its polar edge of 82°9', whereas rutile octahedra only has a polar edge angle of 56°52½'. The steeper angle gives anatase crystals a longer vertical axis and skinnier appearance than rutile. Additional important differences exist between the physical characters of anatase and rutile. For example, anatase is less hard (5.5–6 vs. 6–6.5 on the Mohs scale) and less dense (specific gravity about 3.9 vs. 4.2) than rutile. Anatase is also optically negative, whereas rutile is optically positive. Anatase has a more strongly adamantine or metallic-adamantine luster than that of rutile as well.

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Birefringence in the context of Rutile

Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite.

Rutile has one of the highest refractive indices at visible wavelengths of any known crystal and also exhibits a particularly large birefringence and high dispersion. Owing to these properties, it is useful for the manufacture of certain optical elements, especially polarization optics, for longer visible and infrared wavelengths up to about 4.5 micrometres. Natural rutile may contain up to 10% iron and significant amounts of niobium and tantalum.

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Birefringence in the context of Interference colour chart

In optical mineralogy, an interference colour chart, also known as the Michel-Levy chart, is a tool first developed by Auguste Michel-Lévy to identify minerals in thin section using a petrographic microscope. With a known thickness of the thin section, minerals have specific and predictable colours in cross-polarized light, and this chart can help identify minerals. The colours are produced by the difference in speed in the fast and slow rays, also known as birefringence.

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Birefringence in the context of Levorotation and dextrorotation

Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity. Optical activity occurs only in chiral materials, those lacking microscopic mirror symmetry. Unlike other sources of birefringence which alter a beam's state of polarization, optical activity can be observed in fluids. This can include gases or solutions of chiral molecules such as sugars, molecules with helical secondary structure such as some proteins, and also chiral liquid crystals. It can also be observed in chiral solids such as certain crystals with a rotation between adjacent crystal planes (such as quartz) or metamaterials.

When looking at the source of light, the rotation of the plane of polarization may be either to the right (dextrorotatory or dextrorotaryd-rotary, represented by (+), clockwise), or to the left (levorotatory or levorotaryl-rotary, represented by (−), counter-clockwise) depending on which stereoisomer is dominant. For instance, sucrose and camphor are d-rotary whereas cholesterol is l-rotary. For a given substance, the angle by which the polarization of light of a specified wavelength is rotated is proportional to the path length through the material and (for a solution) proportional to its concentration.

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