Beer–Lambert law in the context of Absorbance


Beer–Lambert law in the context of Absorbance

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⭐ Core Definition: Beer–Lambert law

The Beer–Bouguer–Lambert (BBL) extinction law is an empirical relationship describing the attenuation in intensity of a radiation beam passing through a macroscopically homogenous medium with which it interacts. Formally, it states that the intensity of radiation decays exponentially in the absorbance of the medium, and that said absorbance is proportional to the length of beam passing through the medium, the concentration of interacting matter along that path, and a constant representing said matter's propensity to interact.

The extinction law's primary application is in chemical analysis, where it underlies the Beer–Lambert law, commonly called Beer's law. Beer's law states that a beam of visible light passing through a chemical solution of fixed geometry experiences absorption proportional to the solute concentration. Other applications appear in physical optics, where it quantifies astronomical extinction and the absorption of photons, neutrons, or rarefied gases.

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Beer–Lambert law in the context of Mathematical descriptions of opacity

When an electromagnetic wave travels through a medium in which it gets attenuated (this is called an "opaque" or "attenuating" medium), it undergoes exponential decay as described by the Beer–Lambert law. However, there are many possible ways to characterize the wave and how quickly it is attenuated. This article describes the mathematical relationships among:

Note that in many of these cases there are multiple, conflicting definitions and conventions in common use. This article is not necessarily comprehensive or universal.

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Beer–Lambert law in the context of Air mass (astronomy)

In astronomy, air mass or airmass is a measure of the amount of air along the line of sight when observing a star or other celestial source from below Earth's atmosphere (Green 1992). It is formulated as the integral of air density along the light ray.

As it penetrates the atmosphere, light is attenuated by scattering and absorption; the thicker atmosphere through which it passes, the greater the attenuation. Consequently, celestial bodies when nearer the horizon appear less bright than when nearer the zenith. This attenuation, known as atmospheric extinction, is described quantitatively by the Beer–Lambert law.

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