Azide in the context of Polyatomic anion

Nitrogen is a chemical element; it has symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seventh in total abundance in the Milky Way and the Solar System. At standard temperature and pressure, two atoms of the element bond to form N₂, a colourless and odourless diatomic gas. N₂ forms about 78% of Earth's atmosphere, making it the most abundant chemical species in air. Because of the volatility of nitrogen compounds, nitrogen is relatively rare in the solid parts of the Earth.

It was first discovered and isolated by Scottish physician Daniel Rutherford in 1772 and independently by Carl Wilhelm Scheele and Henry Cavendish at about the same time. The name nitrogène was suggested by French chemist Jean-Antoine-Claude Chaptal in 1790 when it was found that nitrogen was present in nitric acid and nitrates. Antoine Lavoisier suggested instead the name azote, from the Ancient Greek: ἀζωτικός "no life", as it is an asphyxiant gas; this name is used in a number of languages, and appears in the English names of some nitrogen compounds such as hydrazine, azides and azo compounds.

The linear molecular geometry describes the geometry around a central atom bonded to two other atoms (or ligands) placed at a bond angle of 180°. Linear organic molecules, such as acetylene (HC≡CH), are often described by invoking sp orbital hybridization for their carbon centers.

According to the VSEPR model (Valence Shell Electron Pair Repulsion model), linear geometry occurs at central atoms with two bonded atoms and zero or three lone pairs (AX₂ or AX₂E₃) in the AXE notation. Neutral AX₂ molecules with linear geometry include beryllium fluoride (F−Be−F) with two single bonds, carbon dioxide (O=C=O) with two double bonds, hydrogen cyanide (H−C≡N) with one single and one triple bond. The most important linear molecule with more than three atoms is acetylene (H−C≡C−H), in which each of its carbon atoms is considered to be a central atom with a single bond to one hydrogen and a triple bond to the other carbon atom. Linear anions include azide (N=N=N) and thiocyanate (S=C=N), and a linear cation is the nitronium ion (O=N=O).

Hydrazoic acid, also known as hydrogen azide, azic acid or azoimide, is a compound with the chemical formula HN₃. It is a colorless, volatile, and explosive liquid at room temperature and pressure. It is a compound of nitrogen and hydrogen, and is therefore a pnictogen hydride. It was first isolated in 1890 by Theodor Curtius. The acid has few applications, but its conjugate base, the azide ion, is useful in specialized processes.

Hydrazoic acid, like its fellow mineral acids, is soluble in water. Undiluted hydrazoic acid is dangerously explosive with a standard enthalpy of formation Δ_fH (l, 298K) = +264 kJ/mol. When dilute, the gas and aqueous solutions (<10%) can be safely prepared but should be used immediately; because of its low boiling point, hydrazoic acid is enriched upon evaporation and condensation such that dilute solutions incapable of explosion can form droplets in the headspace of the container or reactor that are capable of explosion.

Sodium azide is an inorganic compound with the formula NaN₃. This colorless salt is the gas-forming component in some car airbag systems. It is used for the preparation of other azide compounds. It is highly soluble in water and is acutely poisonous.