Allotrope in the context of "Ozonation"

Ozone (/ˈoʊzoʊn/ ), also called trioxygen, is an inorganic molecule with the chemical formula O
₃. It is a pale-blue gas with a distinctively pungent odour. It is an allotrope of oxygen that is much less stable than the diatomic allotrope O
₂, breaking down in the lower atmosphere to O
₂ (dioxygen). Ozone is formed from dioxygen by the action of ultraviolet (UV) light and electrical discharges within the Earth's atmosphere. It is present in very low concentrations throughout the atmosphere, with its highest concentration high in the ozone layer of the stratosphere, which absorbs most of the Sun's ultraviolet (UV) radiation.

Ozone's odour is reminiscent of chlorine, and detectable by many people at concentrations of as little as 0.1 ppm in air. Ozone's O₃ structure was determined in 1865. The molecule was later proven to have a bent structure and to be weakly diamagnetic. At standard temperature and pressure, ozone is a pale blue gas that condenses at cryogenic temperatures to a dark blue liquid and finally a violet-black solid. Ozone's instability with regard to more common dioxygen is such that both concentrated gas and liquid ozone may decompose explosively at elevated temperatures, physical shock, or fast warming to the boiling point. It is therefore used commercially only in low concentrations.

In chemistry, homonuclear molecules, or elemental molecules, or homonuclear species, are molecules composed of only one element. Homonuclear molecules may consist of various numbers of atoms. The size of the molecule an element can form depends on the element's properties, and some elements form molecules of more than one size. The most familiar homonuclear molecules are diatomic molecules, which consist of two atoms, although not all diatomic molecules are homonuclear. Homonuclear diatomic molecules include hydrogen (H₂), oxygen (O₂), nitrogen (N₂) and all of the halogens. Ozone (O₃) is a common triatomic homonuclear molecule. Homonuclear tetratomic molecules include arsenic (As₄) and phosphorus (P₄).

Allotropes are different chemical forms of the same element (not containing any other element). In that sense, allotropes are all homonuclear. Many elements have multiple allotropic forms. In addition to the most common form of gaseous oxygen, O₂, and ozone, there are other allotropes of oxygen. Sulfur forms several allotropes containing different numbers of sulfur atoms, including diatomic, triatomic, hexatomic and octatomic (S₂, S₃, S₆, S₈) forms, though the first three are rare. The element carbon is known to have a number of homonuclear molecules, including diamond and graphite.

Octasulfur is an inorganic substance with the chemical formula S₈. It is an odourless and tasteless yellow solid, and is a major industrial chemical. It is the most common allotrope of sulfur and occurs widely in nature.

Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous.

Plutonium was first synthesized and isolated in late 1940 and early 1941, by deuteron bombardment of uranium-238 in the 1.5-metre (60 in) cyclotron at the University of California, Berkeley. First, neptunium-238 (half-life 2.1 days) was synthesized, which then beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since uranium had been named after the planet Uranus and neptunium after the planet Neptune, element 94 was named after Pluto, which at the time was also considered a planet. Wartime secrecy prevented the University of California team from publishing its discovery until 1948.