In chemistry, an alkali (/ˈælkəlaɪ/; from the Arabic word al-qāly, القالِي) is a basicsalt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The adjectivealkaline, and less often, alkalescent, is commonly used in English as a synonym for basic, especially for bases soluble in water. This broad use of the term is likely to have come about because alkalis were the first bases known to obey the Arrhenius definition of a base, and they are still among the most common bases.
Ocean acidification is the ongoing decrease in the pH of the Earth's ocean. Between 1950 and 2020, the average pH of the ocean surface fell from approximately 8.15 to 8.05. Carbon dioxide emissions from human activities are the primary cause of ocean acidification, with atmospheric carbon dioxide (CO2) levels exceeding 422 ppm (as of 2024). CO2 from the atmosphere is absorbed by the oceans. This chemical reaction produces carbonic acid (H2CO3) which dissociates into a bicarbonate ion (HCO−3) and a hydrogen ion (H). The presence of free hydrogen ions (H) lowers the pH of the ocean, increasing acidity (this does not mean that seawater is acidic yet; it is still alkaline, with a pH higher than 8). Marine calcifying organisms, such as mollusks and corals, are especially vulnerable because they rely on calcium carbonate to build shells and skeletons.
A change in pH by 0.1 represents a 26% increase in hydrogen ion concentration in the world's oceans (the pH scale is logarithmic, so a change of one in pH units is equivalent to a tenfold change in hydrogen ion concentration). Sea-surface pH and carbonate saturation states vary depending on ocean depth and location. Colder and higher latitude waters are capable of absorbing more CO2. This can cause acidity to rise, lowering the pH and carbonate saturation levels in these areas. There are several other factors that influence the atmosphere-ocean CO2 exchange, and thus local ocean acidification. These include ocean currents and upwelling zones, proximity to large continental rivers, sea ice coverage, and atmospheric exchange with nitrogen and sulfur from fossil fuel burning and agriculture.
In chemistry, pH (/piːˈheɪtʃ/ or /piːˈeɪtʃ/; pee-HAYCH or pee-AYCH) is a logarithmic scale used to specify the acidity or basicity of aqueous solutions. Acidic solutions (solutions with higher concentrations of hydrogen (H) cations) are measured to have lower pH values than basic or alkaline solutions. While the origin of the symbol 'pH' can be traced back to its original inventor, and the 'H' refers clearly to hydrogen, the exact original meaning of the letter 'p' in pH is still disputed; it has since acquired a more general technical meaning that is used in numerous other contexts.
The pH scale is logarithmic and inversely indicates the activity of hydrogen cations in the solution
Sodium hydroxide is a highly corrosivebase and alkali that decomposes lipids and proteins at ambient temperatures, and may cause severe chemical burns at high concentrations. It is highly soluble in water, and readily absorbs moisture and carbon dioxide from the air. It forms a series of hydratesNaOH·nH2O. The monohydrate NaOH·H2O crystallizes from water solutions between 12.3 and 61.8 °C. The commercially available "sodium hydroxide" is often this monohydrate, and published data may refer to it instead of the anhydrous compound.
TAS stands for Total Alkali Silica. The TAS classification can be used to assign names to many common types of volcanic rocks based upon the relationships between the combined alkali and silica contents. These chemical parameters are useful because the relative proportions of alkalis and silica are important in determining both normative mineralogy and actual mineralogy. The classification can be simple to use for rocks that have been chemically analyzed. Except for the following quotation from Johannsen (1937), this discussion is based upon Le Maitre et al (2002).
Quicklime is relatively inexpensive. Both it and the chemical derivative calcium hydroxide (of which quicklime is the base anhydride) are important commodity chemicals.
Alkali in the context of Ultra-high-molecular-weight polyethylene
Ultra-high-molecular-weight polyethylene (UHMWPE, UHMW) is a subset of the thermoplasticpolyethylene. Also known as high-modulus polyethylene (HMPE), it has extremely long chains, with a molecular mass typically between 2 and 6 million daltons. The longer chain serves to transfer load more effectively to the polymer backbone by strengthening intermolecular interactions. This results in a very tough material, with the highest impact strength of any thermoplastic presently made.
UHMWPE is odorless, tasteless, and nontoxic. It embodies all the characteristics of high-density polyethylene (HDPE) with the added traits of being resistant to concentrated acids and alkalis, as well as numerous organic solvents. It is highly resistant to corrosive chemicals except oxidizing acids; has extremely low moisture absorption and a very low coefficient of friction; is self-lubricating (see boundary lubrication); and is highly resistant to abrasion, in some forms being 15 times more resistant to abrasion than carbon steel. Its coefficient of friction is significantly lower than that of nylon and acetal and is comparable to that of polytetrafluoroethylene (PTFE, Teflon), but UHMWPE has better abrasion resistance than PTFE.