Alkali in the context of "Acid-base reaction theories"

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⭐ Core Definition: Alkali

In chemistry, an alkali (/ˈælkəl/ ; from the Arabic word al-qāly, القالِي) is a basic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The adjective alkaline, and less often, alkalescent, is commonly used in English as a synonym for basic, especially for bases soluble in water. This broad use of the term is likely to have come about because alkalis were the first bases known to obey the Arrhenius definition of a base, and they are still among the most common bases.

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Alkali in the context of Ocean acidification

Ocean acidification is the ongoing decrease in the pH of the Earth's ocean. Between 1950 and 2020, the average pH of the ocean surface fell from approximately 8.15 to 8.05. Carbon dioxide emissions from human activities are the primary cause of ocean acidification, with atmospheric carbon dioxide (CO2) levels exceeding 422 ppm (as of 2024). CO2 from the atmosphere is absorbed by the oceans. This chemical reaction produces carbonic acid (H2CO3) which dissociates into a bicarbonate ion (HCO3) and a hydrogen ion (H). The presence of free hydrogen ions (H) lowers the pH of the ocean, increasing acidity (this does not mean that seawater is acidic yet; it is still alkaline, with a pH higher than 8). Marine calcifying organisms, such as mollusks and corals, are especially vulnerable because they rely on calcium carbonate to build shells and skeletons.

A change in pH by 0.1 represents a 26% increase in hydrogen ion concentration in the world's oceans (the pH scale is logarithmic, so a change of one in pH units is equivalent to a tenfold change in hydrogen ion concentration). Sea-surface pH and carbonate saturation states vary depending on ocean depth and location. Colder and higher latitude waters are capable of absorbing more CO2. This can cause acidity to rise, lowering the pH and carbonate saturation levels in these areas. There are several other factors that influence the atmosphere-ocean CO2 exchange, and thus local ocean acidification. These include ocean currents and upwelling zones, proximity to large continental rivers, sea ice coverage, and atmospheric exchange with nitrogen and sulfur from fossil fuel burning and agriculture.

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Alkali in the context of Chemical industry

The chemical industry comprises the companies and other organizations that develop and produce industrial, specialty and other chemicals. Central to the modern world economy, the chemical industry converts raw materials (oil, natural gas, air, water, metals, and minerals) into commodity chemicals for industrial and consumer products. It includes industries for petrochemicals such as polymers for plastics and synthetic fibers; inorganic chemicals such as acids and alkalis; agricultural chemicals such as fertilizers, pesticides and herbicides; and other categories such as industrial gases, speciality chemicals and pharmaceuticals.

Various professionals are involved in the chemical industry including chemical engineers, chemists and lab technicians.

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Alkali in the context of PH

In chemistry, pH (/pˈh/ or /pˈ/; pee-HAYCH or pee-AYCH) is a logarithmic scale used to specify the acidity or basicity of aqueous solutions. Acidic solutions (solutions with higher concentrations of hydrogen (H) cations) are measured to have lower pH values than basic or alkaline solutions. While the origin of the symbol 'pH' can be traced back to its original inventor, and the 'H' refers clearly to hydrogen, the exact original meaning of the letter 'p' in pH is still disputed; it has since acquired a more general technical meaning that is used in numerous other contexts.

The pH scale is logarithmic and inversely indicates the activity of hydrogen cations in the solution

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Alkali in the context of Sodium hydroxide

Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na and hydroxide anions OH.

Sodium hydroxide is a highly corrosive base and alkali that decomposes lipids and proteins at ambient temperatures, and may cause severe chemical burns at high concentrations. It is highly soluble in water, and readily absorbs moisture and carbon dioxide from the air. It forms a series of hydrates NaOH·nH2O. The monohydrate NaOH·H2O crystallizes from water solutions between 12.3 and 61.8 °C. The commercially available "sodium hydroxide" is often this monohydrate, and published data may refer to it instead of the anhydrous compound.

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Alkali in the context of TAS diagram

TAS stands for Total Alkali Silica. The TAS classification can be used to assign names to many common types of volcanic rocks based upon the relationships between the combined alkali and silica contents. These chemical parameters are useful because the relative proportions of alkalis and silica are important in determining both normative mineralogy and actual mineralogy. The classification can be simple to use for rocks that have been chemically analyzed. Except for the following quotation from Johannsen (1937), this discussion is based upon Le Maitre et al (2002).

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Alkali in the context of Calcium oxide

Calcium oxide (formula: CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term lime connotes calcium-containing inorganic compounds, in which carbonates, oxides, and hydroxides of calcium, silicon, magnesium, aluminium, and iron predominate. By contrast, quicklime specifically applies to the single compound calcium oxide. Calcium oxide that survives processing without reacting in building products, such as cement, is called free lime.

Quicklime is relatively inexpensive. Both it and the chemical derivative calcium hydroxide (of which quicklime is the base anhydride) are important commodity chemicals.

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Alkali in the context of Ultra-high-molecular-weight polyethylene

Ultra-high-molecular-weight polyethylene (UHMWPE, UHMW) is a subset of the thermoplastic polyethylene. Also known as high-modulus polyethylene (HMPE), it has extremely long chains, with a molecular mass typically between 2 and 6 million daltons. The longer chain serves to transfer load more effectively to the polymer backbone by strengthening intermolecular interactions. This results in a very tough material, with the highest impact strength of any thermoplastic presently made.

UHMWPE is odorless, tasteless, and nontoxic. It embodies all the characteristics of high-density polyethylene (HDPE) with the added traits of being resistant to concentrated acids and alkalis, as well as numerous organic solvents. It is highly resistant to corrosive chemicals except oxidizing acids; has extremely low moisture absorption and a very low coefficient of friction; is self-lubricating (see boundary lubrication); and is highly resistant to abrasion, in some forms being 15 times more resistant to abrasion than carbon steel. Its coefficient of friction is significantly lower than that of nylon and acetal and is comparable to that of polytetrafluoroethylene (PTFE, Teflon), but UHMWPE has better abrasion resistance than PTFE.

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